Indium-mediated chemoselective deprotection and demonochlorination of 2,2,2-trichloroethyl esters

被引：10

作者：

Mineno, Tomoko ^{[1
]}

Kansui, Hisao ^{[1
]}

Kunieda, Takehisa ^{[1
]}

机构：

[1] Sojo Univ, Fac Pharmaceut Sci, Organ Chem Lab, Kumamoto 860, Japan

来源：

TETRAHEDRON LETTERS | 2007年 / 48卷 / 29期

关键词：

D O I：

10.1016/j.tetlet.2007.05.099

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

On treatment with indium metal, the 2,2,2-trichloroethyl carboxylates smoothly undergo deprotection to carboxylic acids and reductive demonochlorination to 2,27dichloroethyl esters, sharply depending on their structures. (C) 2007 Elsevier Ltd. All rights reserved.

引用

页码：5027 / 5030

页数：4

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