Cobalt-Catalyzed Aerobic Cross-Dehydrogenative Coupling of C-H and Thiols in Water for C-S Formation

被引：75

作者：

Huang, Xin ^{[1
]}

Chen, Yongqi ^{[1
]}

Zhen, Shan ^{[1
]}

Song, Lijuan ^{[1
]}

Gao, Mingqi ^{[2
]}

Zhang, Panke ^{[1
]}

Li, Heng ^{[1
]}

Yuan, Bingxin ^{[1
]}

Yang, Guanyu ^{[1
]}

机构：

[1] Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Henan, Peoples R China

[2] China Tobacco Henan Ind Co Ltd, Zhengzhou 450001, Henan, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2018年 / 83卷 / 14期

基金：

中国国家自然科学基金;

关键词：

SULFUR BOND FORMATION; ORGANOSULFUR COMPOUNDS; ARYL SULFIDES; SULFENYLATING AGENTS; DIRECT THIOLATION; VISIBLE-LIGHT; OXIDATION; INDOLES; FUNCTIONALIZATION; DISULFIDES;

D O I：

10.1021/acs.joc.7b02718

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Organosulfides have great significance and value in synthetic and biological chemistry. To establish a versatile and green methodology for C-S bond generation, we successfully developed a new aerobic cross-dehydrogenative coupling of C-H and S-H to synthesize aryl sulfides in water, utilizing CoPcS as the catalyst and O-2 as the oxidant. This protocol shows great tolerance of a wide range of substrates. A large variety of organosulfur compounds were produced in modest to excellent yields.

引用

页码：7331 / 7340

页数：10

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