Cobalt-Catalyzed Aerobic Cross-Dehydrogenative Coupling of C-H and Thiols in Water for C-S Formation

被引：75
作者：
Huang, Xin [1 ]
Chen, Yongqi [1 ]
Zhen, Shan [1 ]
Song, Lijuan [1 ]
Gao, Mingqi [2 ]
Zhang, Panke [1 ]
Li, Heng [1 ]
Yuan, Bingxin [1 ]
Yang, Guanyu [1 ]
机构：
[1] Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Henan, Peoples R China
[2] China Tobacco Henan Ind Co Ltd, Zhengzhou 450001, Henan, Peoples R China
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2018年 / 83卷 / 14期
基金：
中国国家自然科学基金;
关键词：
SULFUR BOND FORMATION; ORGANOSULFUR COMPOUNDS; ARYL SULFIDES; SULFENYLATING AGENTS; DIRECT THIOLATION; VISIBLE-LIGHT; OXIDATION; INDOLES; FUNCTIONALIZATION; DISULFIDES;
D O I：
10.1021/acs.joc.7b02718
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Organosulfides have great significance and value in synthetic and biological chemistry. To establish a versatile and green methodology for C-S bond generation, we successfully developed a new aerobic cross-dehydrogenative coupling of C-H and S-H to synthesize aryl sulfides in water, utilizing CoPcS as the catalyst and O-2 as the oxidant. This protocol shows great tolerance of a wide range of substrates. A large variety of organosulfur compounds were produced in modest to excellent yields.
引用
收藏
页码：7331 / 7340
页数：10
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