The new decanuclear copper(II) cluster [Cu5(β-alaha)4Cl2]2•2HCl•15H2O, its structure spectroscopy and magnetism

被引：17
|
作者：
Legendziewicz, J.
Puchalska, M.
Ciunik, Z.
Wojciechowski, W.
机构：
[1] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland
[2] Wroclaw Tech Univ, Inst Inorgan Chem & Met Rare Elements, PL-50370 Wroclaw, Poland
来源：
POLYHEDRON | 2007年 / 26卷 / 06期
关键词：
D O I：
10.1016/j.poly.2006.11.002
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The new polynuclear copper(II) cluster with beta-alaninehydroxamic acid of formula [Cu-5(beta-alaha)(4)Cl-2](2) center dot 2HCl center dot 15H(2)O, where beta-alaha stands for beta-alaninehydroxamate (C3H6N2O22- ), was obtained. Single crystals of the complex were growing up in water solution. The cluster is composed of two pentameric subunits joined together by chloride bridges. Magnetic studies showed rather strong spin correlation within pentanuclear clusters and weaker interaction between them. Spectroscopic behavior of the single crystals of the cluster were studied at 293 and 4 K. Strong interactions of copper ions with different symmetry sites and strong electron phonon coupling lead to broad unsplit spectra even at 4 K. (C) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1331 / 1337
页数：7
相关论文
共 50 条
  • [21] Structure of amino copper(II) chloromercurates(II) [Cu(S-HLyS)2]Hg3Cl8•2H2O, [Cu2Cl2(HTren)2]Hg3Cl10•4H2O9 [Cu(En)2]Hg3Cl8, and [Cu(En)2]Hg2Cl6
    Zabel, M
    Poznyak, AL
    Pavlovski, VI
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2005, 50 (12) : 1866 - 1876
  • [22] CRYSTAL STRUCTURE OF DOUBLE SODIUM-COPPER(II) PARATUNGSTATE B, Na2Cu4[W12O40(OH)2]•22H2O, AND MIXED COPPER (II) PARATUNGSTATE B-HYDROXIDE, Cu5[W12O40(OH)2]•2Cu(OH)2•30H2O
    Duvanova, E. S.
    Mariichak, A. Yu.
    Baumer, V. N.
    Rozantsev, G. M.
    Radio, S. V.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2021, 62 (03) : 379 - 389
  • [23] Magneto structural correlations of a 'stepped-wise' discrete tetranuclear unit of copper(II), [Cu4(μ2-OH)2((μ3-OH)2(2,2′-bipy)4Cl2]Cl2•6H2O
    Sain, S
    Maji, TK
    Mostafa, G
    Lu, TH
    Ribas, J
    Tercero, X
    Chaudhuri, NR
    POLYHEDRON, 2003, 22 (04) : 625 - 631
  • [24] Copper azine compounds:: Synthesis, structure and magnetic analyses of Cu(phenazine)Cl2, (phenazinium)2CuCl4 • H2O, and [Cu(phenazine)Cl2 • H2O]2
    Schneider, Ryan T.
    Landee, Christopher P.
    Turnbull, Mark M.
    Awwadi, Firas F.
    Twamley, Brendan
    POLYHEDRON, 2007, 26 (9-11) : 1849 - 1858
  • [25] Polymeric copper(II)-orotato complexes, [(C5H2N2O4)Cu(H2O)2]n
    Ha, TTB
    Larsonneur-Galibert, AM
    Castan, P
    Jaud, J
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 1999, 29 (05) : 565 - 569
  • [26] Polymeric copper(II)-orotato complexes, [(C5H2N2O4)Cu(H2O)2]n
    Tam T.B. Ha
    Anne Marie Larsonneur-Galibert
    Paule Castan
    Joel Jaud
    Journal of Chemical Crystallography, 1999, 29 : 565 - 569
  • [27] Synthesis and crystal Structure of [Cu(TOL)4]Cl2•2C2H5OH•2H2O
    Zhang, PZ
    Wu, J
    Gong, YQ
    Hu, XR
    Gu, JM
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2003, 19 (08) : 909 - 912
  • [28] SCHIFF-BASE LIGANDS FROM 3-AMINOPROPANOL - SYNTHESIS, MAGNETISM, STRUCTURE, AND MASS-SPECTROSCOPY OF BINUCLEAR COPPER(II) COMPLEXES CU2CL2O4N2C20H20, CU2O8N4C20H20, AND CU2O4N2C28H26
    SINN, E
    INORGANIC CHEMISTRY, 1976, 15 (02) : 358 - 365
  • [29] DITHIOSQUARATE COMPLEXES OF COPPER(II) AND COPPER(I) - SYNTHESIS AND CRYSTAL-STRUCTURES OF [CU-II(EN)2][CU-II(C4O2S2)2] AND [CU-II(EN)2(H2O)]2[CU-4-I(C4O2S2)4].2H2O
    KRAUSE, R
    MATTES, R
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1990, 45 (04): : 490 - 496
  • [30] Synthesis, structure and properties of a new copper (II) complex, [Cu2(4,4′-bpy)5(H2O)4](ClO4)4(4,4′-bpy)(DMF)2(H2O)2
    Hu, Feilong
    Yin, Xianhong
    Mi, Yan
    Li, Wanshu
    Tang, Xinping
    Ma, Zhen
    INORGANIC CHEMISTRY COMMUNICATIONS, 2010, 13 (06) : 720 - 723
12345