Fe7S8 Nanoparticles Anchored on Nitrogen-Doped Graphene Nanosheets as Anode Materials for High-Performance Sodium-Ion Batteries

被引:74
作者
He, Qiming [1 ,2 ]
Rui, Kun [1 ]
Yang, Jianhua [1 ,2 ]
Wen, Zhaoyin [1 ,2 ]
机构
[1] Chinese Acad Sci, Shanghai Inst Ceram, CAS Key Lab Mat Energy Convers, Shanghai 200050, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
基金
中国国家自然科学基金; 国家重点研发计划;
关键词
sodium-ion batteries; nitrogen-doped graphene; anode materials; iron sulfides; conversion reaction; SUPERIOR RATE CAPABILITY; TRANSPORT-PROPERTIES; OXIDE COMPOSITE; STORAGE; NANOCOMPOSITE; NANOSTRUCTURES; NANOCRYSTALS; GENERATION; NANOWIRES; CAPACITY;
D O I
10.1021/acsami.8b08237
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Despite high sodium storage capacity and better reversibility, metal sulfides suffer from relatively low conductivity and severe volume change as anode materials of sodium-ion batteries (SIBs). Introducing a conductive carbon matrix is an efficient method to enhance their sodium storage performance. Herein, we present iron sulfide (Fe7S8) nanoparticles anchored on nitrogen-doped graphene nanosheets fabricated through a combined strategy of solvothermal and postheating process. The as-prepared composite exhibits appealing cycling stability (a high discharge capacity of 393.1 mA h g(-1) over 500 cycles at a current density of 400 mA g(-1) and outstanding high-rate performance of 543 mA h even at 10 A g(-1)). Considering the excellent sodium storage performance, this composite is quite hopeful to become a potential candidate as anode materials for future SIBs.
引用
收藏
页码:29476 / 29485
页数:10
相关论文
共 62 条
[31]   Na-Ion Battery Anodes: Materials and Electrochemistry [J].
Luo, Wei ;
Shen, Fei ;
Bommier, Clement ;
Zhu, Hongli ;
Ji, Xiulei ;
Hu, Liangbing .
ACCOUNTS OF CHEMICAL RESEARCH, 2016, 49 (02) :231-240
[32]   Lithiated MoO3 nanobelts with greatly improved performance for lithium batteries [J].
Mai, Liqiang ;
Hu, Bin ;
Chen, Wen ;
Qi, Yanyuan ;
Lao, Changshi ;
Yang, Rusen ;
Dai, Ying ;
Wang, Zhong Lin .
ADVANCED MATERIALS, 2007, 19 (21) :3712-+
[33]   One-step synthesis of hollow C-NiCo2S4 nanostructures for high-performance supercapacitor electrodes [J].
Mohamed, Saad Gomaa ;
Hussain, Iftikhar ;
Shim, Jae-Jin .
NANOSCALE, 2018, 10 (14) :6620-6628
[34]   Sodium Storage and Transport Properties in Layered Na2Ti3O7 for Room-Temperature Sodium-Ion Batteries [J].
Pan, Huilin ;
Lu, Xia ;
Yu, Xiqian ;
Hu, Yong-Sheng ;
Li, Hong ;
Yang, Xiao-Qing ;
Chen, Liquan .
ADVANCED ENERGY MATERIALS, 2013, 3 (09) :1186-1194
[35]   Doping carbons beyond nitrogen: an overview of advanced heteroatom doped carbons with boron, sulphur and phosphorus for energy applications [J].
Paraknowitsch, Jens Peter ;
Thomas, Arne .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (10) :2839-2855
[36]   A magnetically responsive material of single-walled carbon nanotubes functionalized with magnetic ionic liquid [J].
Pei, Xiaowei ;
Yan, Ye Hai ;
Yan, Liangyu ;
Yang, Pan ;
Wang, Junling ;
Xu, Rong ;
Chan-Park, Mary B. .
CARBON, 2010, 48 (09) :2501-2505
[37]   Unique Cobalt Sulfide/Reduced Graphene Oxide Composite as an Anode for Sodium-Ion Batteries with Superior Rate Capability and Long Cycling Stability [J].
Peng, Shengjie ;
Han, Xiaopeng ;
Li, Linlin ;
Zhu, Zhiqiang ;
Cheng, Fangyi ;
Srinivansan, Madhavi U. ;
Adams, Stefan ;
Ramakrishna, Seeram .
SMALL, 2016, 12 (10) :1359-1368
[38]   Enhanced photocatalytic performance of N-doped RGO-FeWO4/Fe3O4 ternary nanocomposite in environmental applications [J].
Sadiq M.M.J. ;
Shenoy U.S. ;
Bhat D.K. .
Materials Today Chemistry, 2017, 4 :133-141
[39]  
Shen K., 2017, ADV ENERGY MAT, V8
[40]   Quantitative measurement of transport properties: Ag-doped nanocrystalline CdS thin films [J].
Singh, Baljinder ;
Singh, Janpreet ;
Kaur, Ramneek ;
Moudgil, R. K. ;
Tripathi, S. K. .
RSC ADVANCES, 2017, 7 (85) :53951-53962