Synthesis and crystal structure of copper(II) bis-chelate comprising a nitrile derivative of 3-imidazoline nitroxide

被引：1

作者：

Burdukov, A. B. ^{[1
]}

Pervukhina, N. V.

Roschupkina, G. I.

Reznikov, V. A.

机构：

[1] Russian Acad Sci, Siberian Div, AV Nikolaev Inst Inorgan Chem, Novosibirsk, Russia

[2] Russian Acad Sci, Siberian Div, NN Vorozhtsov Inst Organ Chem, Novosibirsk, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2007年 / 48卷 / 01期

关键词：

nitroxide radicals; complexes; synthesis; crystal structure;

D O I：

10.1007/s10947-007-0018-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Syntheses of a nitroxide radical 2-(1-oxyl-2,2,5,5-tetramethyl-imidazolin-4-yliden)-3-oxo-5-phenylpentannitrile (HLCH2CH2Ph) and its copper(II) complex are reported. The coordination compound is characterized by the single crystal X-ray diffraction analysis (a = 11.647(2) angstrom, b = 13.269(3) angstrom, c = 13.844(3) angstrom, alpha = 61.83(2) beta = 88.13(2)degrees gamma = 74.12(2)degrees space group P(1) over bar). The Cu(L-CH2CH2Ph)(2)(H2O) complex has a molecular structure.

引用

页码：122 / 127

页数：6

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