Recent progress in functional atom-precise coinage metal clusters protected by alkynyl ligands

被引：90

作者：

Zhang, Miao-Miao ^{[1
]}

Dong, Xi-Yan ^{[1
,2
]}

Wang, Ya-Jie ^{[1
]}

Zang, Shuang-Quan ^{[1
]}

Mak, Thomas C. W. ^{[1
,3
]}

机构：

[1] Zhengzhou Univ, Coll Chem, Green Catalysis Ctr, Henan Key Lab Crystalline Mol Funct Mat,Henan Int, Zhengzhou 450001, Peoples R China

[2] Henan Polytech Univ, Coll Chem & Chem Engn, Jiaozuo 454000, Henan, Peoples R China

[3] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China

来源：

COORDINATION CHEMISTRY REVIEWS | 2022年 / 453卷

基金：

中国国家自然科学基金;

关键词：

Alkynyl ligands; Metal clusters; Luminescence; Chirality; Catalysis; Functionalization; NEAR-INFRARED LUMINESCENCE; STRUCTURAL-CHARACTERIZATION; CHALCOGENIDE CLUSTERS; SILVER(I) CLUSTERS; GOLD NANOCLUSTER; MIXED-VALENCE; AG-I; COMPLEXES; COPPER; PHOSPHORESCENCE;

D O I：

10.1016/j.ccr.2021.214315

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The selection of surface organic ligands is very important for the preparation of coinage metal clusters with precise structures, which can dictate the related properties of metal clusters. Alkynyl ligands, as a class of protecting ligands in metal cluster systems, have been gaining attentions because of the characteristics of both pi and sigma coordination modes. Specially, alkynyl-protected coinage metal clusters possess rich properties. However, there is no review to systemically summarize the functional properties and structure-functionality correlations of alkynyl-protected coinage metal clusters. In this review, the development of alkynyl ligands for the preparation of coinage metal clusters was reviewed. Additionally, the synthetic approaches of the alkynyl-protected coinage metal clusters were provided. Then, the functional properties of the alkynyl-protected coinage metal clusters were comprehensively summarized. In the end, the prospects and opportunities for the future development were discussed. We believed that the review will motivate the development of functionality-oriented alkynyl-protected coinage metal clusters. (C) 2021 Elsevier B.V. All rights reserved.

引用

页数：31

共 179 条

[1] Luminescent high nuclearity Cu(I)-alkynyl clusters, [Cu16(hfac)8(3,3-dimethyl-1-butynyl)8] and [Cu20(hfac)8(3-phenyl-1-propynyl)12] [J].

Baxter, CW ;

Ffiggs, TC ;

Jones, AC ;

Parsons, S ;

Bailey, PJ ;

Tasker, PA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (23) :4395-4401

[2] Direct observation of intersystem crossing in a thermally activated delayed fluorescence copper complex in the solid state [J].

Bergmann, Larissa ;

Hedley, Gordon J. ;

Baumann, Thomas ;

Braese, Stefan ;

Samuel, Ifor D. W. .

SCIENCE ADVANCES, 2016, 2 (01)

[3] Snowman-like silver alkynyl cluster consolidated by templating chloride and peripheral trifluoroacetates [J].

Bian, Shu-Dan ;

Wang, Quan-Ming .

CHEMICAL COMMUNICATIONS, 2008, (43) :5586-5588

[4] A Facile Template Approach to High-Nuclearity Silver(I) Alkynyl Clusters [J].

Bian, Shu-Dan ;

Wu, Hua-Bin ;

Wang, Quan-Ming .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (29) :5363-5365

[5] High-Nuclearity Silver Clusters Templated by Carbonates Generated from Atmospheric Carbon Dioxide Fixation [J].

Bian, Shu-Dan ;

Jia, Jian-Hua ;

Wang, Quan-Ming .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (10) :3422-+

[6] Sustainable metal complexes for organic light-emitting diodes (OLEDs) [J].

Bizzarri, Claudia ;

Spuling, Eduard ;

Knoll, Daniel M. ;

Volz, Daniel ;

Braese, Stefan .

COORDINATION CHEMISTRY REVIEWS, 2018, 373 :49-82

[7] Phosphine-gold(I) derivatives of 1,1′-bis(alkynyl)metallocenes: Molecular structures of Fc'(C=CX)2 [X = Au(PPh3), SiMe3] and Au4{(C=C)2Fc'}2(PPh3)2 [Fc' = Fe(η-C5H4-)2] [J].

Bruce, Michael I. ;

Jevric, Martyn ;

Skelton, Brian W. ;

White, Allan H. ;

Zaitseva, Natasha N. .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2010, 695 (15-16) :1906-1910

[8] Homoleptic transition metal acetylides [J].

Buschbeck, Roy ;

Low, Paul J. ;

Lang, Heinrich .

COORDINATION CHEMISTRY REVIEWS, 2011, 255 (1-2) :241-272

[9] Atomically Precise Clusters of Noble Metals: Emerging Link between Atoms and Nanoparticles [J].

Chakraborty, Indranath ;

Pradeep, Thalappil .

CHEMICAL REVIEWS, 2017, 117 (12) :8208-8271

[10] [Cu13{S2CNnBu2}6(acetylide)4]+: A Two-Electron Superatom [J].

Chakrahari, Kiran Kumarvarma ;

Liao, Jian-Hong ;

Kahlal, Samia ;

Liu, Yu-Chiao ;

Chiang, Ming-Hsi ;

Saillard, Jean-Yves ;

Liu, C. W. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (47) :14704-14708

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