Probing solvation dynamics with femtosecond vibrational spectroscopy

被引：18

作者：

Nibbering, ETJ ^{[1
]}

Elsaesser, T ^{[1
]}

机构：

[1] Max Born Inst Nichtlineare Opt & Kurzzeitspektros, D-12489 Berlin, Germany

来源：

APPLIED PHYSICS B-LASERS AND OPTICS | 2000年 / 71卷 / 03期

关键词：

D O I：

10.1007/s003400000420

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

We explain why solvent reorganization can induce both red- and blue-shifting of vibrational transitions of a particular probe molecule upon excitation to the S-1 electronic state. We observe with femtosecond vibrational spectroscopy, after hydrogen-bond cleavage dynamics, an additional blue shift of the carbonyl stretch of coumarin 102 of 7 cm(-1) when dissolved in chloroform.

引用

页码：439 / 441

页数：3

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