NiCoO2 nanosheets grown on nitrogen-doped porous carbon sphere as a high-performance anode material for lithium-ion batteries

被引:20
作者
Sun, Ruixue [1 ]
Zhang, Yezhen [1 ]
Tang, Yufeng [1 ]
Li, Yabei [1 ]
Ding, Shujiang [2 ]
Liu, Xiaodi [1 ]
机构
[1] Nanyang Normal Univ, Coll Chem & Pharm Engn, Nanyang 473061, Peoples R China
[2] Xi An Jiao Tong Univ, Dept Appl Chem, Sch Sci,State Key Lab Mech Behav Mat, MOE Key Lab Nonequilibrium Synth & Modulat Conden, Xian 710049, Peoples R China
基金
中国国家自然科学基金;
关键词
NiCoO2; Nanosheets; N-doped; Porous carbon; Lithium-ion batteries; FACILE SYNTHESIS; ELECTRODE MATERIALS; STORAGE; NICO2O4; GRAPHENE; OXIDE; NANOCOMPOSITES; NANOSTRUCTURES; NANOPARTICLES; CHALLENGES;
D O I
10.1016/j.ijhydene.2017.03.165
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
NiCoO2 nanosheets grown on nitrogen-doped porous carbon spheres (NiCoO2@N-PCs) have been synthesized via a facile approach using gelatin nanospheres (GNSs) as the template, carbon and nitrogen sources. Due to the synergistic effect between the NiCoO2 nanosheets and N-PCs, the NiCoO2@N-PCs composite exhibits an ultrahigh discharge capacity of 978 mAh g(-1) at a current density of 200 mA g(-1) with minimal capacity loss even after 80 cycles. The superior properties of NiCoO2@N-PCs illustrate that amorphous carbon matrix could significantly improve the electrochemical performance of high-capacity metal oxide anode nanomaterials. Findings from this study suggest that these GNSs may be used to synthesize functional metal oxides, including MnO2, Fe2O3, CoO and NiO@N-PCs nanostructures. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:13150 / 13157
页数:8
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