Recent Advances in Living Cationic Polymerization with Emerging Initiation/Controlling Systems

被引：30
作者：
Chen, Yinan [1 ]
Zhang, Lu [1 ,2 ]
Jin, Yi [2 ]
Lin, Xinrong [2 ]
Chen, Mao [1 ]
机构：
[1] Fudan Univ, Dept Macromol Sci, State Key Lab Mol Engn Polymers, Shanghai 200433, Peoples R China
[2] Yunnan Univ, Sch Chem Sci & Technol, Yunnan Prov Ctr Res & Dev Nat Prod, Key Lab Med Chem Nat Resource,Minist Educ, Kunming 650091, Yunnan, Peoples R China
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 2021年 / 42卷 / 13期
基金：
中国国家自然科学基金;
关键词：
catalysis; cationic RAFT polymerization; living cationic polymerization; photocontrolled polymerization; vinyl ethers; ISOBUTYL VINYL ETHER; STAR-SHAPED POLYMERS; RAFT POLYMERIZATION; POLY(VINYL ETHER)S; RADICAL POLYMERIZATION; BLOCK-COPOLYMERS; VISIBLE-LIGHT; CARBOCATIONIC POLYMERIZATION; ORGANOALUMINUM HALIDES; CONJUGATED POLYMERS;
D O I：
10.1002/marc.202100148
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
While the conventional living cationic polymerization (LCP) provided opportunities to synthesizing well-defined polymers with predetermined molecular weights, desirable chemical structures and narrow dispersity, it is still important to continuously innovate new synthetic methods to meet the increasing requirements in advanced material engineering. Consequently, a variety of novel initiation/controlling systems have be demonstrated recently, which have enabled LCP with spatiotemporal control, broadened scopes of monomers and terminals, more user-friendly operations and reaction conditions, as well as improved thermomechanical properties for obtained polymers. In this work, recent advances in LCP is summarized with emerging initiation/controlling systems, including chemical-initiated/controlled cationic reversible addition-fragmentation chain transfer (RAFT) polymerization, photoinitiated/controlled LCP, electrochemical-controlled LCP, thionyl/selenium halide-initiated LCP, organic acid-assisted LCP, and stereoselective LCP. It is hoped that this summary will provide useful knowledge to people in related fields and stimulate new ideas to promote the development and application of LCP in both academia and industry.
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页数：14
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