Clean preparation of S-thiocarbamates with in situ generated hydroxide in 2-methyltetrahydrofuran

被引：63
作者：
Bao, Wen-Hu [1 ]
Wang, Zheng [1 ]
Tang, Xiao [1 ]
Zhang, Yun-Fu [1 ]
Tan, Jia-Xi [1 ,3 ]
Zhu, Qin [2 ]
Cao, Zhong [2 ]
Lin, Ying-Wu [4 ]
He, Wei-Min [1 ]
机构：
[1] Hunan Univ Sci & Engn, Dept Chem, Yongzhou 425100, Peoples R China
[2] Changsha Univ Sci & Technol, Hunan Prov Key Lab Mat Protect Elect Power & Tran, Changsha 410114, Peoples R China
[3] Hunan Univ Sci & Technol, Sch Chem & Chem Engn, Xiangtan 411201, Peoples R China
[4] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China
来源：
CHINESE CHEMICAL LETTERS | 2019年 / 30卷 / 12期
关键词：
Green chemistry; Hydroxide; Biomass; S-Thiocarbamates; 2-Methyltetrahydrofuran; INDUCED DEOXYGENATIVE C2-SULFONYLATION; QUINOLINE N-OXIDES; IONIC LIQUID; 3-COMPONENT REACTION; EFFICIENT SYNTHESIS; FACILE SYNTHESIS; CATALYST-FREE; DERIVATIVES; DESIGN; SULFUR;
D O I：
10.1016/j.cclet.2019.06.052
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A simple and clean protocol for the synthesis of various alkyl and (hetero)aryl S-thiocarbamates was established. The usage of in situ generated hydroxide as both an oxygen source and hydrogen source as well as biomass-derived 2-methyltetrahydrofuran as a green reaction medium, the avoidance of phosphorus-containing reductant, and the generation of harmless water and nitrogen as the side-products have given the present method atom-economy and environmental friendliness. (C) 2019 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：2259 / 2262
页数：4
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