Synthesis and Structure of Triphenylbismuth Dicarboxylates Ph3Bi[OC(O)R]2 (R = CH2C6H4F-3, C6H3F2-2,3, C6HF4-2,3,4,5)

被引：1

作者：

Sharutin, V. V. ^{[1
]}

Sharutina, O. K. ^{[1
]}

Koscheeva, L., V ^{[1
]}

机构：

[1] Natl Res South Ural State Univ, Chelyabinsk 454080, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2021年 / 91卷 / 05期

关键词：

triphenylbismuth dicarboxylates; X-ray diffraction studies; ANTILEISHMANIAL ACTIVITY; COMPARATIVE STABILITY; TOXICITY; COMPLEXES;

D O I：

10.1134/S1070363221050133

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bismuth compounds Ph3Bi[OC(O)R](2) (R = CH2C6H4F-3, C6H3F2-2,3, C6HF4-2,3,4,5) were synthesized by the reaction of triphenylbismuth with a carboxylic acid and tert-butyl hydroperoxide (1 : 2 : 1 mol.) in diethyl ether. Structural features of these compounds were determined by the single crystal X-ray analysis method. Bismuth atoms in triphenylbismuth dicarboxylates have distorted trigonal-bipyramidal coordination with oxygen atoms in axial positions. The presence of intramolecular contacts Bi center dot center dot center dot O(=C) [2.833(8)-3.136(9) angstrom] causes an increase in one of CBiC bond angles to 151.07(15)degrees, 142.0(3)degrees, 138.53(14)degrees, respectively, due to a decrease in the other two angles.

引用

页码：840 / 843

页数：4

共 21 条

[1] Bioactive Heteroleptic Bismuth(V) Complexes: Synthesis, Structural Analysis and Binding Pattern Validation [J].

Andleeb, Sohaila ;

Imtiaz-ud-Din ;

Rauf, Muhammad Khawar ;

Azam, Syed Sikander ;

Haq, Ihsan-ul ;

Tahir, Muhammad Nawaz ;

Ahmad, Sajjad .

APPLIED ORGANOMETALLIC CHEMISTRY, 2019, 33 (09)

[2]

BATSANOV SS, 1991, ZH NEORG KHIM+, V36, P3015

[3] Antimony(V) and Bismuth(V) Complexes of Lapachol: Synthesis, Crystal Structure and Cytotoxic Activity [J].

de Oliveira, Ludmila G. ;

Silva, Meiriane M. ;

de Paula, Flavia C. S. ;

Pereira-Maia, Elene C. ;

Donnici, Claudio L. ;

de Simone, Carlos A. ;

Frezard, Frederic ;

da Silva Junior, Eufranio N. ;

Demicheli, Cynthia .

MOLECULES, 2011, 16 (12) :10314-10323

[4]

DODONOV VA, 1985, ZH OBSHCH KHIM+, V55, P73

[5] OLEX2: a complete structure solution, refinement and analysis program [J].

Dolomanov, Oleg V. ;

Bourhis, Luc J. ;

Gildea, Richard J. ;

Howard, Judith A. K. ;

Puschmann, Horst .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2009, 42 :339-341

[6] Comparative stability, cytotoxicity and anti-leishmanial activity of analogous organometallic Sb(V) and Bi(V) acetato complexes: Sb confirms potential while Bi fails the test [J].

Duffin, Rebekah N. ;

Blair, Victoria L. ;

Kedzierski, Lukasz ;

Andrews, Philip C. .

JOURNAL OF INORGANIC BIOCHEMISTRY, 2018, 189 :151-162

[7] Comparative stability, toxicity and anti-leishmanial activity of triphenyl antimony(V) and bismuth(V) α-hydroxy carboxylato complexes [J].

Duffin, Rebekah N. ;

Blair, Victoria L. ;

Kedzierski, Lukasz ;

Andrews, Philip C. .

DALTON TRANSACTIONS, 2018, 47 (03) :971-980

[8]

Gusakovskaya A.A., 2018, KRISTALLOGRAFIYA+, V63, P203, DOI [10.7868/S0023476118020066, DOI 10.7868/S0023476118020066]

[9] Synthesis and structure of triphenylantinony dimethacrylate [J].

Gushchin, A. V. ;

Shashkin, D. V. ;

Prytkova, L. K. ;

Somov, N. V. ;

Baranov, E. V. ;

Shavyrin, A. S. ;

Rykalin, V. I. .

RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2011, 81 (03) :493-496

[10]

Gushchin F. V., 2016, B S URAL STATE U SER, V8, P51, DOI [10.14529/chem160108, DOI 10.14529/CHEM160108]

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