Thermotropic phase transition in an adsorbed melissic acid film at the n-hexane-water interface

被引：3
|
作者：
Tikhonov, A. M. [1 ]
机构：
[1] Russian Acad Sci, Kapitza Inst Phys Problems, Moscow 119334, Russia
来源：
JETP LETTERS | 2017年 / 105卷 / 12期
关键词：
X-RAY-SCATTERING; CHAIN MOLECULES; VAPOR INTERFACE; SURFACE; FLUOROALKANOL; REFLECTIVITY; IONS; FLUCTUATIONS; MONOLAYERS; MIXTURE;
D O I：
10.1134/S002136401712013X
中图分类号：
O4 [物理学];
学科分类号：
0702 ;
摘要：
A reversible thermotropic phase transition in an adsorption melissic acid film at the interface between n-hexane and an aqueous solution of potassium hydroxide (pH ae 10) is investigated by X-ray reflectometry and diffuse scattering using synchrotron radiation. The experimental data indicate that the interface "freezing" transition is accompanied not only by the crystallization of the Gibbs monolayer but also by the formation of a planar smectic structure in the similar to 300--thick adsorption film; this structure is formed by similar to 50--thick layers.
引用
收藏
页码：775 / 781
页数：7
相关论文
共 50 条
  • [21] Impact of intensity of ultrasonication on the properties of n-hexane-water emulsion
    Hameed, Gulzar
    Baloch, Musa Kaleem
    Nawaz, Mohsan
    Rehman, Wajid
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2011, 85 (05) : 792 - 796
  • [22] X-Ray Study of Thermotropic Mesophases of an Adsorbed n-Triacontanol Film at the n-Hexadecane-Water Interface
    Tikhonov, A. M.
    JETP LETTERS, 2017, 106 (11) : 743 - 748
  • [23] X-Ray Study of Thermotropic Mesophases of an Adsorbed n-Triacontanol Film at the n-Hexadecane–Water Interface
    A. M. Tikhonov
    JETP Letters, 2017, 106 : 743 - 748
  • [24] Experimental Investigation of PVT-Dependence of n-Hexane-Water System
    High Temp, 3 (485):
  • [25] Comment on "Phase transition in adsorption layers at the water/hexane interface"
    Aratono, M
    Hayami, Y
    Takiue, T
    JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (17): : 4560 - 4561
  • [26] Effect of ω-hydrogenation on the adsorption of fluorononanols at the hexane/water interface:: Miscibility in the adsorbed film of fluorononanols
    Murakami, D
    Takata, Y
    Matsubara, H
    Aratono, M
    Takiue, T
    JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (47): : 22366 - 22370
  • [27] Experimental investigation of PVT-dependence of n-hexane-water system
    Rasulov, SM
    HIGH TEMPERATURE, 1997, 35 (03) : 485 - 489
  • [28] Effect of Hydrophobic Chain Structure on Phase Transition and Domain Formation of Hybrid Alcohol Films Adsorbed at the Hexane/Water Interface
    Mitani, Kenta
    Imai, Yosuke
    Ina, Toshiaki
    Nitta, Kiyofumi
    Tanida, Hajime
    Uruga, Tomoya
    Matsubara, Hiroki
    Aratono, Makoto
    Takiue, Takanori
    JOURNAL OF PHYSICAL CHEMISTRY B, 2015, 119 (38): : 12436 - 12445
  • [29] Saturated Vapor Pressure over the Azeotropic Mixture of the n-Hexane-Water System
    Russ J Phys Chem, 1 (83):
  • [30] Molecular dynamics study of the n-hexane-water interface:: Towards a better understanding of the liquid-liquid interfacial broadening
    Nicolas, JP
    de Souza, NR
    JOURNAL OF CHEMICAL PHYSICS, 2004, 120 (05): : 2464 - 2469
12345