Copper immobilized ferromagnetic nanoparticle triazine dendrimer (FMNP@TD-Cu(II))-catalyzed regioselective synthesis of 1,4-disubstituted 1,2,3-triazoles

被引:42
|
作者
Bahrami, Kiumars [1 ,2 ]
Arabi, Mehdi Sheikh [1 ]
机构
[1] Razi Univ, Fac Chem, Dept Organ Chem, Kermanshah 6714967436, Iran
[2] Razi Univ, NNRC, Kermanshah 6714967436, Iran
关键词
SOLID-PHASE SYNTHESIS; AZIDE-FREE CONDITIONS; ONE-POT; CLICK-CHEMISTRY; HIGHLY EFFICIENT; METAL-FREE; MAGNETIC NANOPARTICLES; CYCLOADDITION REACTION; RECYCLABLE CATALYST; REUSABLE CATALYST;
D O I
10.1039/c5nj03219a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A copper immobilized ferromagnetic nanoparticle triazine dendrimer (FMNP@TD-Cu(II)) has been demonstrated for the first time as a recoverable and reusable heterogeneous nanocatalyst in the click synthesis of 1,4-disubstituted 1,2,3-triazoles by a one-pot three component reaction of halides, sodium azides and alkynes under mild conditions. The catalyst is very easy to handle and is environmentally safe and economical. FMNP@TD-Cu(II) was characterized using transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray diffraction (XRD), FT-IR and EDX methods.
引用
收藏
页码:3447 / 3455
页数:9
相关论文
共 50 条
  • [41] Synthesis of disubstituted 1,2,3-triazoles via copper(I)-catalyzed cycloaddition
    Calvin, Marcus I.
    Hamill, Brayden D.
    Mueller, Joann E.
    Schoffstall, Allen M.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 243
  • [42] Synthesis and antimicrobial evaluation of some novel thiomorpholine derived 1,4-disubstituted 1,2,3-triazoles
    Battula, Kumaraswamy
    Narsimha, Sirassu
    Nagavelli, Vasudevareddy
    Bollepelli, Priyanka
    Rao, Mutheneni Srinivasa
    JOURNAL OF THE SERBIAN CHEMICAL SOCIETY, 2016, 81 (03) : 233 - 242
  • [43] Conventional and microwave assisted synthesis of 1,4-disubstituted 1,2,3-triazoles from Huisgen cycloaddition
    Sarmiento-Sanchez, Juan I.
    Ochoa-Teran, Adrian
    Rivero, Ignacio A.
    ARKIVOC, 2011, : 177 - 188
  • [44] Recent Catalysts Used in the Synthesis of 1,4-Disubstituted 1,2,3-Triazoles by Heterogeneous and Homogeneous Methods
    Noriega, Saul
    Leyva, Elisa
    Moctezuma, Edgar
    Flores, Luisa
    Loredo-Carrillo, Silvia
    CURRENT ORGANIC CHEMISTRY, 2020, 24 (05) : 536 - 549
  • [45] Efficient synthesis, antitubercular and antimicrobial evaluation of 1,4-disubstituted 1,2,3-triazoles with amide functionality
    C. P. Kaushik
    Ashima Pahwa
    Dharmendra Singh
    Krishan Kumar
    Raj Luxmi
    Monatshefte für Chemie - Chemical Monthly, 2019, 150 : 1127 - 1136
  • [46] Design, synthesis, anticancer and antioxidant activities of amide linked 1,4-disubstituted 1,2,3-triazoles
    Kaushik, C. P.
    Sangwan, Jyoti
    Luxmi, Raj
    Kumar, Devinder
    Kumar, Deepak
    Das, Ashutosh
    Kumar, Ashwani
    Singh, Dharmendra
    JOURNAL OF MOLECULAR STRUCTURE, 2021, 1226
  • [47] One-Pot Synthesis of 1,4-Disubstituted 1,2,3-Triazoles from Aldehydes and Amines
    Maisonneuve, Stephane
    Xie, Juan
    SYNLETT, 2009, (18) : 2977 - 2981
  • [48] Design, synthesis, characterization and antimicrobial evaluation of amide tagged 1,4-disubstituted 1,2,3-triazoles
    Yadav, Archna
    Kaushik, C. P.
    Yadav, Priyanka
    Yadav, Jyoti
    SYNTHETIC COMMUNICATIONS, 2023, 53 (22) : 1902 - 1917
  • [49] Efficient synthesis, antitubercular and antimicrobial evaluation of 1,4-disubstituted 1,2,3-triazoles with amide functionality
    Kaushik, C. P.
    Pahwa, Ashima
    Singh, Dharmendra
    Kumar, Krishan
    Luxmi, Raj
    MONATSHEFTE FUR CHEMIE, 2019, 150 (06): : 1127 - 1136
  • [50] Azide/Alkyne Resins for Quick Preparation of 1,4-Disubstituted 1,2,3-Triazoles
    Sirion, Uthaiwan
    Lee, Jae Hak
    Bae, Yu Jin
    Kim, Hee Jun
    Lee, Byoung Se
    Chi, Dae Yoon
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2010, 31 (07) : 1843 - 1847