Copper immobilized ferromagnetic nanoparticle triazine dendrimer (FMNP@TD-Cu(II))-catalyzed regioselective synthesis of 1,4-disubstituted 1,2,3-triazoles

被引:42
|
作者
Bahrami, Kiumars [1 ,2 ]
Arabi, Mehdi Sheikh [1 ]
机构
[1] Razi Univ, Fac Chem, Dept Organ Chem, Kermanshah 6714967436, Iran
[2] Razi Univ, NNRC, Kermanshah 6714967436, Iran
关键词
SOLID-PHASE SYNTHESIS; AZIDE-FREE CONDITIONS; ONE-POT; CLICK-CHEMISTRY; HIGHLY EFFICIENT; METAL-FREE; MAGNETIC NANOPARTICLES; CYCLOADDITION REACTION; RECYCLABLE CATALYST; REUSABLE CATALYST;
D O I
10.1039/c5nj03219a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A copper immobilized ferromagnetic nanoparticle triazine dendrimer (FMNP@TD-Cu(II)) has been demonstrated for the first time as a recoverable and reusable heterogeneous nanocatalyst in the click synthesis of 1,4-disubstituted 1,2,3-triazoles by a one-pot three component reaction of halides, sodium azides and alkynes under mild conditions. The catalyst is very easy to handle and is environmentally safe and economical. FMNP@TD-Cu(II) was characterized using transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray diffraction (XRD), FT-IR and EDX methods.
引用
收藏
页码:3447 / 3455
页数:9
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