Continuous wave free precession - Practical analytical tool for low-resolution nuclear magnetic resonance measurements

被引:34
作者
Azeredo, RBV
Colnago, LA
Souza, AA
Engelsberg, M
机构
[1] Embrapa Instrumentacao Agropecuaria, BR-13560970 Sao Carlos, SP, Brazil
[2] Univ Sao Paulo, Inst Quim, BR-13560970 Sao Carlos, SP, Brazil
[3] Univ Fed Pernambuco, Dept Fis, BR-50670901 Recife, PE, Brazil
[4] Univ Fed Fluminense, Inst Quim, BR-24020150 Niteroi, RJ, Brazil
基金
巴西圣保罗研究基金会;
关键词
NMR; SSFP; CWFP; oil analysis; moisture analysis;
D O I
10.1016/S0003-2670(02)01514-3
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The use of continuous wave free precession (CWFP) as a practical analytical tool for quantitative determinations in low-resolution nuclear magnetic resonance (LRNMR) is examined. The requirements of this technique are shown to be no more demanding than those prevailing in free-induction decay or spin-echo measurements. It is shown that the substantial gain in signal to noise ratio for a given acquisition time permitted by CWFP, can be exploited with advantage in practically any application of LRNMR. This applies not only to homogeneous low viscosity liquid samples but also to multi-component systems where differences in relaxation times of each component permit a separation of the individual contributions. As an example, the use of CWFP for fast quantitative determination of oil and moisture in various seeds is presented. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:313 / 320
页数:8
相关论文
共 12 条
  • [1] Flow sensitivity and coherence in steady-state free spin precession
    De Vasconcellos Azeredo, R.B.
    Engelsberg, M.
    Colnago, L.A.
    [J]. Physical Review E - Statistical, Nonlinear, and Soft Matter Physics, 2001, 64 (1 II): : 1 - 016309
  • [2] Azeredo RBD, 2000, ANAL CHEM, V72, P2401
  • [3] STEADY-STATE FREE PRECESSION IN NUCLEAR MAGNETIC RESONANCE
    CARR, HY
    [J]. PHYSICAL REVIEW, 1958, 112 (05): : 1693 - 1701
  • [4] Cho SI, 1997, T ASAE, V40, P1129, DOI 10.13031/2013.21330
  • [5] APPLICATION OF FOURIER TRANSFORM SPECTROSCOPY TO MAGNETIC RESONANCE
    ERNST, RR
    ANDERSON, WA
    [J]. REVIEW OF SCIENTIFIC INSTRUMENTS, 1966, 37 (01) : 93 - +
  • [6] PHASE AND INTENSITY ANOMALIES IN FOURIER TRANSFORM NMR
    FREEMAN, R
    HILL, HDW
    [J]. JOURNAL OF MAGNETIC RESONANCE, 1971, 4 (03) : 366 - &
  • [7] Process NMR spectrometry
    Nordon, A
    McGill, CA
    Littlejohn, D
    [J]. ANALYST, 2001, 126 (02) : 260 - 272
  • [8] Low-field 1H nuclear magnetic resonance and chemometrics combined for simultaneous determination of water, oil, and protein contents in oilseeds
    Pedersen, HT
    Munck, L
    Engelsen, SB
    [J]. JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 2000, 77 (10) : 1069 - 1076
  • [9] SIMULTANEOUS DETERMINATION OF OIL AND WATER CONTENTS IN DIFFERENT OILSEEDS BY PULSED NUCLEAR-MAGNETIC-RESONANCE
    RUBEL, G
    [J]. JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1994, 71 (10) : 1057 - 1062
  • [10] Scheffler K, 1999, CONCEPT MAGNETIC RES, V11, P291, DOI 10.1002/(SICI)1099-0534(1999)11:5<291::AID-CMR2>3.0.CO