Precision Polymers through ADMET Polymerization

被引：97
作者：
Schulz, Michael D. [1 ,2 ,3 ,4 ,5 ]
Wagener, Kenneth B. [1 ,2 ,6 ,7 ]
机构：
[1] Univ Florida, Dept Chem, George & Josephine Butler Polymer Res Lab, Gainesville, FL 32611 USA
[2] Univ Florida, Ctr Macromol Sci & Engn, Gainesville, FL 32611 USA
[3] Kyoto Univ, Kyoto 6068501, Japan
[4] Harvard Univ, Cambridge, MA 02138 USA
[5] Max Planck Inst Polymer Res, Grp Klaus Mullen, D-55128 Mainz, Germany
[6] Univ Florida, Gainesville, FL 32611 USA
[7] Ctr Macromol Sci & Engn, Arlington, VA USA
来源：
MACROMOLECULAR CHEMISTRY AND PHYSICS | 2014年 / 215卷 / 20期
关键词：
ADMET polymerization; Grubbs catalyst; olefin metathesis; precision polymers; ACYCLIC DIENE METATHESIS; IMIDO ALKYLIDENE COMPLEXES; TELECHELIC POLYBUTADIENE OLIGOMERS; OLEFIN METATHESIS; ETHYLENE/PROPYLENE COPOLYMERS; FUNCTIONALIZED POLYOLEFINS; RENEWABLE RESOURCES; BRANCH FREQUENCY; MOLECULAR-WEIGHT; THERMAL-BEHAVIOR;
D O I：
10.1002/macp.201400268
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Acyclic diene metathesis (ADMET) polymerization is a unique strategy for achieving polymers with precise control over the primary structure. This precision is obtained by specific monomer design and carefully controlled polymerization conditions. Over time, this approach has produced an array of sophisticated architectures ranging from precise polyethylenes, to hyperbranched polymers, to rotaxanes.
引用
收藏
页码：1936 / 1945
页数：10
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