One-step degradation of cellulose to 5-hydroxymethylfurfural in ionic liquid under mild conditions

被引：66

作者：

Zhou, Lilong ^{[1
]}

He, Yiming ^{[2
]}

Ma, Zhanwei ^{[1
]}

Liang, Runjuan ^{[1
]}

Wu, Tinghua ^{[1
]}

Wu, Ying ^{[1
]}

机构：

[1] Zhejiang Normal Univ, Inst Phys Chem, Minist Educ Adv Catalysis Mat, Key Lab, Jinhua 321004, Peoples R China

[2] Zhejiang Normal Univ, Dept Mat Phys, Jinhua 321004, Peoples R China

来源：

CARBOHYDRATE POLYMERS | 2015年 / 117卷

基金：

中国国家自然科学基金;

关键词：

Cellulose; 5-Hydroxymethylfurfural; Ionic liquid; CrCl3; CONVERSION; CHLORIDE; WATER;

D O I：

10.1016/j.carbpol.2014.10.062

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

One-step conversion of cellulose to HMF (5-hydroxymethylfurfural) has been achieved by using metal chlorides (CrCl3, CuCl2, SnCl4, WCl6) in [BMIM]Cl. The effects of temperature, reaction time, amount of catalysts, and the purity of [BMIM]Cl on the performance have been studied and discussed in detail. More than 63% yield of HMF and 80% yield of TRS (total reducing sugar) were obtained in [BMIM]Cl with CrCl3 at 120 degrees C under atmospheric pressure. Filter paper and cotton were also used as a source for cellulose degradation to HMF, but only a moderate yield of HMF was obtained (40% for filter paper and 12% for cotton). The reutilization of this system was examined and the reaction mechanism was also discussed. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：694 / 700

页数：7

共 23 条

[1] Microwave assisted conversion of carbohydrates and biopolymers to 5-hydroxymethylfurfural with aluminium chloride catalyst in water
De, Sudipta
Dutta, Saikat
Saha, Basudeb
[J]. GREEN CHEMISTRY, 2011, 13 (10) : 2859 - 2868
[2] The mechanism of glucose conversion to 5-hydroxymethylfurfural catalyzed by metal chlorides in ionic liquid: A theoretical study
Guan, Jing
Cao, Quan
Guo, Xingcui
Mu, Xindong
[J]. COMPUTATIONAL AND THEORETICAL CHEMISTRY, 2011, 963 (2-3) : 453 - 462
[3] Conversion of fructose and glucose into 5-hydroxymethylfurfural with lignin-derived carbonaceous catalyst under microwave irradiation in dimethyl sulfoxide-ionic liquid mixtures
Guo, Feng
Fang, Zhen
Zhou, Tie-Jun
[J]. BIORESOURCE TECHNOLOGY, 2012, 112 : 313 - 318
[4] Ionic liquids as reaction medium in cellulose functionalization
Heinze, T
Schwikal, K
Barthel, S
[J]. MACROMOLECULAR BIOSCIENCE, 2005, 5 (06) : 520 - 525
[5] Cellulose nanopaper structures of high toughness
Henriksson, Marielle
Berglund, Lars A.
Isaksson, Per
Lindstrom, Tom
Nishino, Takashi
[J]. BIOMACROMOLECULES, 2008, 9 (06) : 1579 - 1585
[6] Efficient Conversion of Glucose into 5-Hydroxymethylfurfural by Chromium(III) Chloride in Inexpensive Ionic Liquid
Hu, Lei
Sun, Yong
Lin, Lu
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2012, 51 (03) : 1099 - 1104
[7] Efficient conversion of glucose into 5-hydroxymethylfurfural catalyzed by a common Lewis acid SnCl4 in an ionic liquid
Hu, Suqin
Zhang, Zhaofu
Song, Jinliang
Zhou, Yinxi
Han, Buxing
[J]. GREEN CHEMISTRY, 2009, 11 (11) : 1746 - 1749
[8] Production of 5-hydroxymethylfurfural in ionic liquids under high fructose concentration conditions
Li, Changzhi
Zhao, Zongbao K.
Wang, Aiqin
Zheng, Mingyuan
Zhang, Tao
[J]. CARBOHYDRATE RESEARCH, 2010, 345 (13) : 1846 - 1850
[9] Crystal structure and hydrogen bonding system in cellulose 1α, from synchrotron X-ray and neutron fiber diffraction
Nishiyama, Y
Sugiyama, J
Chanzy, H
Langan, P
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (47) : 14300 - 14306
[10] Ionic liquids and catalysis: Recent progress from knowledge to applications
Olivier-Bourbigou, H.
Magna, L.
Morvan, D.
[J]. APPLIED CATALYSIS A-GENERAL, 2010, 373 (1-2) : 1 - 56

← 1 2 3 →