Ionic liquids as solvents for polymerization processes-Progress and challenges

被引：333

作者：

Kubisa, Przemyslaw ^{[1
]}

机构：

[1] Polish Acad Sci, Ctr Mol & Macromol Studies, PL-90363 Lodz, Poland

来源：

PROGRESS IN POLYMER SCIENCE | 2009年 / 34卷 / 12期

关键词：

Ionic liquids; Polycondensation; Radical polymerization; Ionic polymerization; Solvent properties; FREE-RADICAL POLYMERIZATION; RING-OPENING POLYMERIZATION; N-ETHYLPYRROLIDINIUM DICYANAMIDE; CHARGE-TRANSFER POLYMERIZATION; DIFFUSION-CONTROLLED REACTIONS; METHYL-METHACRYLATE; MICROWAVE IRRADIATION; CATIONIC-POLYMERIZATION; ANIONIC-POLYMERIZATION; LIVING POLYMERIZATION;

D O I：

10.1016/j.progpolymsci.2009.09.001

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Ionic liquids (ILs) are organic salts that are liquid at ambient temperatures. Ionic liquids have emerged as a new class of solvents for practical applications due to their unique combination of low volatility, chemical stability, high conductivity, wide electrochemical window, ability to dissolve organic and inorganic solutes and gases, and tunable solvent properties. In polymer science ionic liquids are used as solvents for polymerization processes and as components of polymeric materials. In this review the advantages and limitations of application of ionic liquids as solvents for polymerization processes are critically discussed, with special emphasis on results published within last 5 years. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：1333 / 1347

页数：15

共 177 条

[91] Soluble New Optically Active Polyamides Derived from 5-(4-Methyl-2-phthalimidylpentanoylamino)isophthalic acid and Different Diisocyanates Under Microwave Irradiation in Molten Ionic Liquid [J].

Mallakpour, Shadpour ;

Dinari, Mohammad .

JOURNAL OF APPLIED POLYMER SCIENCE, 2009, 112 (01) :244-253

[92] Molten Tetrabutylammonium Bromide as Eco-Friendly Media for the Synthesis of Optically Active and Thermal Stable Polyamides under Microwave Irradiation [J].

Mallakpour, Shadpour ;

Taghavi, Mehdi .

POLYMER JOURNAL, 2008, 40 (11) :1049-1059

[93] Enzymatic polyester synthesis in ionic liquids [J].

Marcilla, Rebeca ;

de Geus, Matthijs ;

Mecerreyes, David ;

Duxbury, Christopher J. ;

Koning, Cor E. ;

Heise, Andreas .

EUROPEAN POLYMER JOURNAL, 2006, 42 (06) :1215-1221

[94] The structure of a room-temperature ionic liquid with and without trace amounts of water:: The role of C-H•••O and C-H•••F interactions in 1-n-butyl-3-methylimidazolium tetrafluoroborate [J].

Mele, A ;

Tran, CD ;

Lacerda, SHD .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (36) :4364-4366

[95] Graft copolymers prepared by atom transfer radical polymerization (ATRP) from cellulose [J].

Meng, Tao ;

Gao, Xia ;

Zhang, Jun ;

Yuan, Jinying ;

Zhang, Yuzhu ;

He, Jiasong .

POLYMER, 2009, 50 (02) :447-454

[96] Ring-opening polymerization of γ-benzyl-L-glutamate-N-carboxyanhydride in ionic liquids [J].

Mori, Hideharu ;

Iwata, Mizuki ;

Ito, Satoko ;

Endo, Takeshi .

POLYMER, 2007, 48 (20) :5867-5877

[97] GLOSSARY OF TERMS USED IN PHYSICAL ORGANIC-CHEMISTRY [J].

MULLER, P .

PURE AND APPLIED CHEMISTRY, 1994, 66 (05) :1077-1184

[98] Preparation of cellulose-polymerized ionic liquid composite by in-situ polymerization of polymerizable ionic liquid in cellulose-dissolving solution [J].

Murakami, Masa-aki ;

Kaneko, Yoshiro ;

Kadokawa, Jun-ichi .

CARBOHYDRATE POLYMERS, 2007, 69 (02) :378-381

[99] Ionic liquids in carbohydrate chemistry - Current trends and future directions [J].

Murugesan, S ;

Linhardt, RJ .

CURRENT ORGANIC SYNTHESIS, 2005, 2 (04) :437-451

[100]

Nelson WM, 2002, ACS SYM SER, V818, P30

← 5 6 7 8 9 10 11 12 13 14 →