Effects of Solvent Diols on the Synthesis of ZnFe2O4 Particles and Their Use as Heterogeneous Photo-Fenton Catalysts

被引：55
作者：
Anchieta, Chayene Goncalves [1 ]
Cancelier, Adriano [1 ]
Mazutti, Marcio Antonio [1 ]
Jahn, Sergio Luiz [1 ]
Kuhn, Raquel Cristine [1 ]
Guendel, Andre [2 ]
Chiavone-Filho, Osvaldo [3 ]
Foletto, Edson Luiz [1 ]
机构：
[1] Univ Fed Santa Maria, Dept Chem Engn, BR-97105900 Santa Maria, RS, Brazil
[2] Fed Univ Pampa, Dept Phys, BR-96413170 Bage, Brazil
[3] Univ Fed Rio Grande do Norte, Dept Chem Engn, BR-59066800 Natal, RN, Brazil
来源：
MATERIALS | 2014年 / 7卷 / 09期
关键词：
zinc ferrite; ZnFe2O4; synthesis; solvothermal; photo-Fenton; ZINC FERRITE; FACILE SYNTHESIS; MAGNETIC-PROPERTIES; PHOTOCATALYTIC DEGRADATION; NANOPARTICLES; BEHAVIOR; ROUTE;
D O I：
10.3390/ma7096281
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A solvothermal method was used to prepare zinc ferrite spinel oxide (ZnFe2O4) using ethylene glycol and 1,4 butanediol as solvent diols, and the influence of diols on the physical properties of ZnFe2O4 particles was investigated. The produced particles were characterized by X-ray powder diffraction (XRD), atomic force microscopy (AFM), Fourier transform infrared spectroscopy (FTIR) and nitrogen adsorption isotherms, and the catalytic activity for the organic pollutant decomposition by heterogeneous photo-Fenton reaction was investigated. Both solvents produced particles with cubic spinel structure. Microporous and mesoporous structures were obtained when ethylene glycol and 1,4 butanediol were used as diols, respectively. A higher pore volume and surface area, as well as a higher catalytic activity for the pollutant degradation were found when 1,4 butanediol was used as solvent.
引用
收藏
页码：6281 / 6290
页数：10
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