X-ray study of modulated structure in [N(CH3)4]2CuCl4 under high pressure

被引:3
作者
Asahi, T [1 ]
Izutsu, K [1 ]
机构
[1] Yamaguchi Univ, Fac Sci, Dept Phys Biol & Informat, Yamaguchi 7538512, Japan
关键词
N(CH3)(4)](2)CuCl4; incommensurate phase; modulated structure; pressure; phase transition; X-ray diffraction;
D O I
10.1143/JPSJ.72.330
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Pressure-temperature dependence of modulation wavenumber of [N(CH3)(4)](2)CuCl4 was measured with X-ray diffraction method in the region of 22 less than or equal to T less than or equal to 160degreesC, 0.25 less than or equal to p less than or equal to 0.95 GPa. Two commensurate phases with modulation wavenumber q = 3/8 and 2/5 were found within the pressure-induced incommensurate phase. The phase q = 3/8 is identified as the high-pressure ferroelectric phase F-2 found by Gesi.
引用
收藏
页码:330 / 334
页数:5
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