Dye-sensitized solar cells, based on electrochemically functionalized porphyrins

被引：6

作者：

Adineh, Maryam ^{[1
]}

Tahay, Pooya ^{[1
]}

Shahrjerdi, Akram ^{[1
]}

Davarani, Seyed Saeed Hoseini ^{[1
]}

Safari, Nasser ^{[1
]}

机构：

[1] Shahid Beheshti Univ, Dept Chem, Tehran 1983963113, Iran

来源：

JOURNAL OF THE IRANIAN CHEMICAL SOCIETY | 2016年 / 13卷 / 07期

基金：

美国国家科学基金会;

关键词：

Dye-sensitized solar cells; Porphyrincatechol; Electrochemically functionalized porphyrin; Indirect electron injection pathway; PHOTOINDUCED ELECTRON-TRANSFER; CHARGE-TRANSFER SENSITIZERS; ZINC PHTHALOCYANINES; ANCHORING GROUP; ORGANIC-DYE; TIO2; CATECHOL; CONVERSION; PHOTOSENSITIZERS; EFFICIENCY;

D O I：

10.1007/s13738-016-0850-x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The applications of electrochemically functionalized porphyrin have been considered in dye-sensitized solar cells (DSSCs). A porphyrin-catechol derivative has been electrochemically functionalized with a sulfur-contained, 2-mercaptobenzothiazole moiety and was tested as dye. Catechol moiety acts as the anchoring group in these types of dyes. The IPCE result confirmed that photocurrents for DSSCs based on porphyrin-catechol dyes are mainly generated by an indirect electron injection pathway (Type I mechanism).The cells made with this porphyrin were stable and showed no significant desorption of dye from the TiO2 surface after days. Electrochemically functionalized porphyrin-catechol showed almost 100 % enhancement in efficiency compared to bare porphyrin-catechol. The effect of different additives on cell performance was also tested. Electrochemically functionalized porphyrin catechol, in the presence of chenodeoxycholic acid had a record performance with a conversion efficiency of 0.6 % under AM 1.5 irradiation. A porphyrincatechol derivative has been prepared via electrosynthesis with a sulfur contained, 2-mercaptobenzothiazole moiety and was tested as dye. Catechol moiety acts as the anchoring group in these types of dyes. The IPCE result confirmed that photocurrents for DSSCs based on porphyrincatechol dyes are mainly generated by an indirect electron-injection pathway (Type I mechanism). [GRAPHICS] .

引用

页码：1357 / 1365

页数：9

共 68 条

[11] Influence of Phenylethynylene of Push-Pull Zinc Porphyrins on the Photovoltaic Performance [J].

Chou, Hsien-Hsin ;

Reddy, Kamani Sudhir K. ;

Wu, Hui-Ping ;

Guo, Bo-Cheng ;

Lee, Hsuan-Wei ;

Diau, Eric Wei-Guang ;

Hsu, Chao-Ping ;

Yeh, Chen-Yu .

ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (05) :3418-3427

[12] The role of porphyrin chemistry in tumor imaging and photodynamic therapy [J].

Ethirajan, Manivannan ;

Chen, Yihui ;

Joshi, Penny ;

Pandey, Ravindra K. .

CHEMICAL SOCIETY REVIEWS, 2011, 40 (01) :340-362

[13] Photoelectrochemical cells [J].

Grätzel, M .

NATURE, 2001, 414 (6861) :338-344

[14] Highly selective, economical and efficient oxidation of alcohols to aldehydes and ketones by air and sunlight or visible light in the presence of porphyrins sensitizers [J].

Hajimohammadi, Mahdi ;

Safari, Nasser ;

Mofakham, Hamid ;

Deyhimi, Farzad .

GREEN CHEMISTRY, 2011, 13 (04) :991-997

[15] Advancing beyond current generation dye-sensitized solar cells [J].

Hamann, Thomas W. ;

Jensen, Rebecca A. ;

Martinson, Alex B. F. ;

Van Ryswyk, Hal ;

Hupp, Joseph T. .

ENERGY & ENVIRONMENTAL SCIENCE, 2008, 1 (01) :66-78

[16] Organized assemblies of single wall carbon nanotubes and porphyrin for photochemical solar cells: Charge injection from excited porphyrin into single-walled carbon nanotubes [J].

Hasobe, Taku ;

Fukuzumi, Shunichi ;

Kamat, Prashant V. .

JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (50) :25477-25484

[17] Effects of meso-Diarylamino Group of Porphyrins as Sensitizers in Dye-Sensitized Solar Cells on Optical, Electrochemical, and Photovoltaic Properties [J].

Imahori, Hiroshi ;

Matsubara, Yusuke ;

Iijima, Hiroaki ;

Umeyama, Tomokazu ;

Matano, Yoshihiro ;

Ito, Seigo ;

Niemi, Marja ;

Tkachenko, Nikolai V. ;

Lemmetyinen, Helge .

JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (23) :10656-10665

[18] Effects of Porphyrin Substituents and Adsorption Conditions on Photovoltaic Properties of Porphyrin-Sensitized TiO2 Cells [J].

Imahori, Hiroshi ;

Hayashi, Shinya ;

Hayashi, Hironobu ;

Oguro, Akane ;

Eu, Seunghun ;

Umeyama, Tomokazu ;

Matano, Yoshihiro .

JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (42) :18406-18413

[19] Fabrication of thin film dye sensitized solar cells with solar to electric power conversion efficiency over 10% [J].

Ito, Seigo ;

Murakami, Takurou N. ;

Comte, Pascal ;

Liska, Paul ;

Graetzel, Carole ;

Nazeeruddin, Mohammad K. ;

Graetzel, Michael .

THIN SOLID FILMS, 2008, 516 (14) :4613-4619

[20] A new facile electrochemical method for functionalization of porphyrin [J].

Jamaat, Parisa Rajabali ;

Davarani, Saied Saeed Hosseiny ;

Fumani, Neda Sheijooni ;

Masourni, Leila ;

Safari, Nasser .

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2008, 12 (02) :85-93

← 1 2 3 4 5 6 7 →