Effects of microwave irradiation on the decane-water interface in the presence of Triton X-100

被引:21
|
作者
Hyde, Anita [1 ,2 ]
Horiguchi, Masahiro [3 ]
Minamishima, Naoya [3 ]
Asakuma, Yusuke [3 ]
Phan, Chi [1 ,2 ]
机构
[1] Curtin Univ, Nanochem Res Inst, GPO Box U1987, Perth, WA 6845, Australia
[2] Curtin Univ, Dept Chem Engn, GPO Box U1987, Perth, WA 6845, Australia
[3] Univ Hyogo, Grad Sch Engn, 2167 Shosha, Himeji, Hyogo 6712280, Japan
关键词
Interfacial tension; Triton X-100; Drop shape analysis; Microwave; De-emulsification; CRUDE OIL-EMULSIONS; TEMPERATURE-DEPENDENCE; SURFACE-TENSION; DEMULSIFICATION; SALINITY; PRESSURE; MICELLES; BEHAVIOR; NUMBER; SIZE;
D O I
10.1016/j.colsurfa.2017.04.044
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The present work investigates the influence of heating methods on the interfacial tension of the decane-water interface in the presence of the common industrial surfactant, Triton X-100. The work considers heating by conventional methods, such as a waterbath, in contrast to microwave irradiation. Use of the holm interface allowed the measurement of interfacial tension even during irradiation. The interfacial tension was found to increase as the samples were heated from 25 to 65 degrees C by the two methods. However, microwaves were found to elicit changes to the response of interfacial tension to changing temperature, resulting in a much more dramatic increase in interfacial tension. The impact of microwaves can be attributed to different networks of hydrogen bonding between surfactant and water at the interface and in the bulk.
引用
收藏
页码:178 / 184
页数:7
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