USE OF MANGANESE OXIDES RECOVERED FROM SPENT BATTERIES IN ELECTROCATALYSIS OF OXYGEN REDUCTION REACTION IN ALKALINE MEDIUM.

被引:4
作者
Rascio, Daniel C. [1 ]
De Souza, Rodrigo F. B. [1 ]
Teixeira Neto, Erico [1 ]
Suffredini, Hugo B. [1 ]
Santos, Mauro C. [1 ]
Calegaro, Marcelo L. [2 ]
机构
[1] Univ Fed ABC, Ctr Ciencias Nat & Humanas, Rua Santa Adelia 166, BR-09210170 Santo Andre, SP, Brazil
[2] Univ Sao Paulo, Inst Quim Sao Carlos, BR-13560970 Sao Carlos, SP, Brazil
来源
QUIMICA NOVA | 2010年 / 33卷 / 03期
关键词
manganese oxide; oxygen reduction; battery metal recovery; ELECTRODE MATERIALS; OXIDATION REACTION; COMPOSITES; CATALYSTS; BEHAVIOR; METHANOL; ZINC;
D O I
10.1590/S0100-40422010000300043
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
USE OF MANGANESE OXIDES RECOVERED FROM SPENT BATTERIES IN ELECTROCATALYSIS OF OXYGEN REDUCTION REACTION IN ALKALINE MEDIUM. The oxygen reduction reaction was studied in alkaline media using manganese oxides obtained from spent batteries as electrocatalysts. Three processes were used to recover manganese oxides from spent batteries. The particles obtained were in the range from 8 to 11 nm. The electrochemical experiments indicated a good electrocatalytic activity toward oxygen reduction using the different samples and showing approximately a direct transference of 4 electrons during the process. Even though all the processes were efficient, the best result was observed for the prepared sample using reactants of low cost.
引用
收藏
页码:730 / 733
页数:4
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