Extended structures of three new coordination polymers based on 1,10-phenanthroline derivatives and 1,4-benzenedicarboxylate mixed ligands: Preparation, structural characterization and properties

被引：21

作者：

Wang, Xiu-Li ^{[1
]}

Chen, Yong-Qiang ^{[1
]}

Liu, Guo-Cheng ^{[1
]}

Zhang, Jin-Xia ^{[1
]}

Lin, Hong-Yan ^{[1
]}

Chen, Bao-Kuan ^{[1
]}

机构：

[1] Bohai Univ, Fac Chem & Chem Engn, Jinzhou 121000, Liaoning, Peoples R China

来源：

INORGANICA CHIMICA ACTA | 2010年 / 363卷 / 04期

基金：

中国国家自然科学基金;

关键词：

Hydrothermal syntheses; Crystal structure; 1,10-Phenanthroline derivatives; Fluorescence Electrochemistry; CRYSTAL-STRUCTURES; COPPER(II) COMPLEXES; ORGANIC COMPOUNDS; FRAMEWORKS; ELECTROCHEMISTRY; ARCHITECTURES; FLUORESCENCE; SERIES; 1-D;

D O I：

10.1016/j.ica.2009.11.038

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three coordination polymers, namely, [Cd(HOIP)(2)(1,4-bdc)] (1), [Cu(HOIP)(1,4-bdc)] (2) and [Cu(PDIP)-(1,4-bdc)] (3) (HOIP = 2-(4-hydroxylbenzene) imidazo[4,5-f] 1,10-phenanthroline, PDIP = 2-(3-pyridine) imidazo[4,5-f] 1,10-phenanthroline, and 1,4-bdc = 1,4-benzenedicarboxylate), have been synthesized under the hydrothermal conditions. All complexes have been characterized by elemental analyses, IR and single-crystal X-ray diffraction. Structural analyses reveal that complex 1 possesses infinite one-dimensional (1D) chain bridged by 1,4-bdc ligands, complexes 2 and 3 both exhibit two-dimensional (2D) (4,4) network structures based on dinuclear [Cu2O2] units. However, the weak interactions are different in complexes 1-3. Moreover, the thermal properties of all complexes, fluorescence property of 1, and the electrochemical behavior of 3 are also reported in this paper. (C) 2009 Elsevier B. V. All rights reserved.

引用

页码：773 / 778

页数：6

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