The mechanical properties of elastomers with chemical and physical junctions

被引：0

作者：

Solovjev, MY ^{[1
]}

Kapranov, VA ^{[1
]}

Irzhak, VI ^{[1
]}

Galushko, AG ^{[1
]}

机构：

[1] YAROSLAVL STATE UNIV, YAROSLAVL 150053, RUSSIA

来源：

GELS-BOOK | 1996年 / 102卷

关键词：

elastomers; networks physical junctions; mechanical properties;

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Theoretical model of the mechanical properties of elastomer network with thermoreversible junctions have been obtained on the basis of nonequilibrium thermodynamics and physical kinetics methods. Non-Gaussian assumption for a free energy of chains in the equilibrium state have been used As was established, the possibility of construction of the tearing master-curve is determined by the energy of junctions. If the energy of junctions is less then 60 kJ/mol the time-temperature superposition principle contravenes and anomalous large fracture work is observed. II was found that ultimate tensile strength versus junctions energy curve has a maximum. Thus, an optimal value of junctions energy exists.

引用

页码：86 / 88

页数：3