Click chemistry strategies for the accelerated synthesis of functional macromolecules

被引：201

作者：

Geng, Zhishuai ^{[1
,2
]}

Shin, Jaeman J. ^{[1
,3
]}

Xi, Yumeng ^{[1
]}

Hawker, Craig J. ^{[1
,4
,5
]}

机构：

[1] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA

[2] Beijing Inst Technol, Sch Mat Sci & Engn, Beijing, Peoples R China

[3] Soongsil Univ, Dept Organ Mat & Fiber Engn, Seoul, South Korea

[4] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

[5] Univ Calif Santa Barbara, Dept Mat, Santa Barbara, CA 93106 USA

来源：

JOURNAL OF POLYMER SCIENCE | 2021年 / 59卷 / 11期

基金：

美国国家科学基金会;

关键词：

click chemistry; macromolecules; synthesis; polymerization; postpolymerization modification; AZIDE-ALKYNE CYCLOADDITION; THIOL-ENE CLICK; OPENING METATHESIS POLYMERIZATION; DIELS-ALDER REACTION; CHAIN TRANSFER POLYMERIZATION; STAR-BLOCK-COPOLYMERS; ONE-POT SYNTHESIS; NITRILE N-OXIDES; TRANSFER RADICAL POLYMERIZATION; AGGREGATION-INDUCED EMISSION;

D O I：

10.1002/pol.20210126

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Click chemistry is one of the most powerful strategies for constructing polymeric soft materials with precise control over architecture and functionality. In this review, we provide a comprehensive summary of the state-of-the art for synthesizing functional polymers and their expanding range of applications. The synthetic and mechanistic aspects are discussed for key reactions that fulfill "click" requirements and their applications in construction of macromolecules with linear, branched, and other complex architectures are described.

引用

页码：963 / 1042

页数：80

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