Recent developments in the utilization of green solvents in polymer chemistry

被引:173
作者
Erdmenger, Tina [1 ,2 ]
Guerrero-Sanchez, Carlos [1 ,2 ]
Vitz, Juergen [2 ,3 ]
Hoogenboom, Richard [1 ,2 ]
Schubert, Ulrich S. [1 ,2 ,3 ]
机构
[1] Eindhoven Univ Technol, Lab Macromol Chem & Nanosci, NL-5600 MB Eindhoven, Netherlands
[2] Dutch Polymer Inst, NL-5600 AX Eindhoven, Netherlands
[3] Univ Jena, Lab Organ & Macromol Chem, D-07743 Jena, Germany
关键词
TRANSFER RADICAL POLYMERIZATION; RING-OPENING POLYMERIZATION; SUPERCRITICAL CARBON-DIOXIDE; TEMPERATURE IONIC LIQUIDS; LIFE-CYCLE ASSESSMENT; MICROWAVE-ASSISTED SYNTHESIS; NEAR-CRITICAL WATER; DISPERSION POLYMERIZATION; METHYL-METHACRYLATE; CATIONIC-POLYMERIZATION;
D O I
10.1039/b909964f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The use of solvents produces the largest amount of auxiliary waste in polymer science. Due to the fact that sustainable chemistry is becoming more and more important in polymer research, alternative reaction media have been investigated in order to reduce or replace the use of organic solvents. The most commonly used green solvents in polymer chemistry are water, supercritical carbon dioxide and ionic liquids. The progress of utilizing these green solvents in polymerization processes is reviewed and discussed in this critical review on the basis of results mainly published during the last five years (216 references).
引用
收藏
页码:3317 / 3333
页数:17
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