Recent developments in the utilization of green solvents in polymer chemistry

被引：173

作者：

Erdmenger, Tina ^{[1
,2
]}

Guerrero-Sanchez, Carlos ^{[1
,2
]}

Vitz, Juergen ^{[2
,3
]}

Hoogenboom, Richard ^{[1
,2
]}

Schubert, Ulrich S. ^{[1
,2
,3
]}

机构：

[1] Eindhoven Univ Technol, Lab Macromol Chem & Nanosci, NL-5600 MB Eindhoven, Netherlands

[2] Dutch Polymer Inst, NL-5600 AX Eindhoven, Netherlands

[3] Univ Jena, Lab Organ & Macromol Chem, D-07743 Jena, Germany

来源：

CHEMICAL SOCIETY REVIEWS | 2010年 / 39卷 / 08期

关键词：

TRANSFER RADICAL POLYMERIZATION; RING-OPENING POLYMERIZATION; SUPERCRITICAL CARBON-DIOXIDE; TEMPERATURE IONIC LIQUIDS; LIFE-CYCLE ASSESSMENT; MICROWAVE-ASSISTED SYNTHESIS; NEAR-CRITICAL WATER; DISPERSION POLYMERIZATION; METHYL-METHACRYLATE; CATIONIC-POLYMERIZATION;

D O I：

10.1039/b909964f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of solvents produces the largest amount of auxiliary waste in polymer science. Due to the fact that sustainable chemistry is becoming more and more important in polymer research, alternative reaction media have been investigated in order to reduce or replace the use of organic solvents. The most commonly used green solvents in polymer chemistry are water, supercritical carbon dioxide and ionic liquids. The progress of utilizing these green solvents in polymerization processes is reviewed and discussed in this critical review on the basis of results mainly published during the last five years (216 references).

引用

页码：3317 / 3333

页数：17

共 217 条

[1]

Adams D.J., 2004, Chemistry in Alternative Reaction Media

[2] Electrochemical synthesis and surface characterization of poly(3,4-ethylenedioxythiophene) films grown in an ionic liquid [J].