Inhibitory influence of cationic Gemini surfactant on the dissolution rate of N80 carbon steel in 15% HCl solution

被引:47
作者
Deyab, M. A. [1 ]
Mohsen, Q. [2 ]
机构
[1] Egyptian Petr Res Inst EPRI, Cairo, Egypt
[2] Taif Univ, Coll Sci, Dept Chem, At Taif, Saudi Arabia
关键词
GREEN CORROSION-INHIBITOR; MILD-STEEL; HYDROCHLORIC-ACID; IONIC LIQUIDS; ELECTROCHEMICAL INVESTIGATIONS; PERFORMANCE; DERIVATIVES; ADSORPTION; PROTECTION; COPPER;
D O I
10.1038/s41598-021-90031-x
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Strong acids are commonly used in petroleum wells to remove scale layers from the surface of N80 C-steel pipe. The corrosive effects of these acids, on the other hand, pose a significant risk to C-steel pipes. For the first time, we discovered the anti-corrosion properties of cationic Gemini surfactant, 1,2-bis(dodecyldimethylammonio) ethane dibromide (DMAEB), for N80 C-steel pipe in acid washing solution (15.0% HCl). The DMAEB, in particular, can reduce the corrosion rate of N80 C-steel by approximately 97%. DMAEB molecules work as a mixed-type corrosion inhibitor, according to electrochemical results. The DMAEB demonstrated a high inhibition effect at high temperatures, as well as high activation energy against the corrosion process. DMAEB's significant performance is primarily due to physical adsorption on the N80 C-steel surface, as confirmed by adsorption isotherms, SEM, EDX, FT-IR, and theoretical studies. Our findings shed new light on the use of Gemini surfactants as corrosion inhibitors in petroleum wells.
引用
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页数:12
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