Fluorescent chemosensor for detection of Zn2+ and Cu2+ and its application in molecular logic gate

被引:30
作者
Qin, Jing-can [1 ]
Yang, Zheng-yin [1 ]
机构
[1] Lanzhou Univ, State Key Lab Appl Organ Chem, Coll Chem & Chem Engn, Lanzhou 730000, Peoples R China
基金
中国国家自然科学基金;
关键词
Fluorescent probe; Coumarin; Naphthalene; Zn2+/Cu2+; ESIPT; TURN-ON; NANOMOLAR DETECTION; SENSOR; ZINC; PROBE; AL3+; COPPER(II); IONS; DISEASE; BASE;
D O I
10.1016/j.jphotochem.2016.03.029
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this study, a novel naphthalene schiff-base as a dual-analyte fluorescent sensor for Zn2+ and Cu2+ has been designed and synthesized. The sensor shows significant fluorescence enhancement in the presence of Zn2+, which might be attributed to inhibit ESIPT process, in contrast, its fluorescence is quenched by Cu2+ owing to its inherent to the magnetic property. More interestingly, we have successfully utilized the two metal ions (Cu2+ and Zn2+) as chemical inputs for the manufacture of INHIBIT type logic gate. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:152 / 158
页数:7
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