Heterogeneous Catalysis by Polyoxometalates in Metal-Organic Frameworks

被引:303
作者
Samaniyan, Maryam [1 ]
Mirzaei, Masoud [1 ]
Khajavian, Ruhollah [1 ]
Eshtiagh-Hosseini, Hossein [1 ]
Streb, Carsten [2 ,3 ]
机构
[1] Ferdowsi Univ Mashhad, Fac Sci, Dept Chem, Mashhad, Razavi Khorasan, Iran
[2] Ulm Univ, Inst Inorgan Chem 1, Albert Einstein Allee 11, D-89081 Ulm, Germany
[3] Helmholtz Inst Ulm, Helmholtzstr 11, D-89081 Ulm, Germany
来源
ACS CATALYSIS | 2019年 / 9卷 / 11期
关键词
polyoxometalates; metal-organic frameworks; composites; heterogeneous catalysis; metal oxides; OXIDATIVE DESULFURIZATION PROCESS; PROTON-CONDUCTING PATHWAYS; ONE-POT SYNTHESIS; X-RAY-STRUCTURE; PHOSPHOTUNGSTIC ACID; HIGHLY EFFICIENT; SELECTIVE OXIDATION; HYBRID MATERIAL; MOLECULAR-OXYGEN; FACILE SYNTHESIS;
D O I
10.1021/acscatal.9b03439
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The embedding of molecular metal oxides, or polyoxometalates (POMs), in metal-organic frameworks (MOFs) opens new research avenues in catalysis and beyond. This review explores the host-guest chemistry of POMs embedded in MOF hosts and discusses the synergism of the resulting composites for heterogeneous catalysis. The review focuses on well-established and well-studied classes of POMs, such as Keggin and Wells-Dawson anions, and well-researched MOFs, including the MIL, UiO, and NENU families. Outstanding examples of synergistic catalytic activity between the POM and MOF are described, and key performance parameters, including POM localization, pore size and pore structure, as well as particle size effects are described for technologically important catalytic processes. In addition to thermal catalysis, we discuss the use of POM@MOF composites for electro- and photocatalysis with an emphasis on energy conversion systems. Finally, we provide an outlook on emerging areas where POM@MOF composites could lead to new catalytic reactivity.
引用
收藏
页码:10174 / 10191
页数:35
相关论文
共 172 条
[1]   POM@IL-MOFs - inclusion of POMs in ionic liquid modified MOFs to produce recyclable oxidation catalysts [J].
Abednatanzi, Sara ;
Leus, Karen ;
Derakhshandeh, Parviz Gohari ;
Nahra, Fady ;
De Keukeleere, Katrien ;
Van Hecke, Kristof ;
Van Driessche, Isabel ;
Abbasi, Alireza ;
Nolan, Steven P. ;
Van Der Voort, Pascal .
CATALYSIS SCIENCE & TECHNOLOGY, 2017, 7 (07) :1478-1487
[2]   Adsorptive denitrogenation of model fuels with porous metal-organic framework (MOF) MIL-101 impregnated with phosphotungstic acid: Effect of acid site inclusion [J].
Ahmed, Imteaz ;
Khan, Nazmul Abedin ;
Hasan, Zubair ;
Jhung, Sung Hwa .
JOURNAL OF HAZARDOUS MATERIALS, 2013, 250 :37-44
[3]   Pushing the Limits on Metal-Organic Frameworks as a Catalyst Support: NU-1000 Supported Tungsten Catalysts for o-Xylene Isomerization and Disproportionation [J].
Ahn, Sol ;
Nauert, Scott L. ;
Buru, Cassandra T. ;
Rimoldi, Martino ;
Choi, Hyeju ;
Schweitzer, Neil M. ;
Hupp, Joseph T. ;
Farha, Omar K. ;
Notestein, Justin M. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140 (27) :8535-8543
[4]  
[Anonymous], 2016, INORG CHEM RES
[5]  
[Anonymous], 2019, INORG CHEM RES
[6]  
[Anonymous], J MAL STRUCT
[7]  
[Anonymous], 2019, ANGEW CHEM INT EDIT, DOI DOI 10.1002/anie.201803868
[8]  
[Anonymous], TRENDS CHEM
[9]  
[Anonymous], NEW J CHEM
[10]  
[Anonymous], 2017, ANGEW CHEM INT ED