Negative thermal expansion: Mechanisms and materials

被引:116
作者
Liang, Erjun [1 ,2 ]
Sun, Qiang [1 ,2 ]
Yuan, Huanli [1 ,2 ]
Wang, Jiaqi [1 ,2 ]
Zeng, Gaojie [1 ,2 ]
Gao, Qilong [1 ,2 ]
机构
[1] Zhengzhou Univ, Minist Educ China, Key Lab Mat Phys, Zhengzhou 450001, Peoples R China
[2] Zhengzhou Univ, Sch Phys & Microelect, Zhengzhou 450001, Peoples R China
基金
中国国家自然科学基金; 中国博士后科学基金;
关键词
negative thermal expansion; mechanisms of thermal contraction; negative thermal expansion materials; lattice thermal dynamics; magnetovolume effect; ferroelectrostriction; charge transfer; anisotropic elasticity; RIGID-UNIT MODES; ORTHORHOMBIC PHASE-TRANSITION; INELASTIC NEUTRON-SCATTERING; WIDE TEMPERATURE-RANGE; SPONTANEOUS POLARIZATION; CRYSTAL WATER; PRESSURE-DEPENDENCE; VALENCE TRANSITION; RAMAN-SPECTROSCOPY; MAGNETIC-STRUCTURE;
D O I
10.1007/s11467-021-1070-0
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Negative thermal expansion (NTE) of materials is an intriguing phenomenon challenging the concept of traditional lattice dynamics and of importance for a variety of applications. Progresses in this field develop markedly and update continuously our knowledge on the NTE behavior of materials. In this article, we review the most recent understandings on the underlying mechanisms (anharmonic phonon vibration, magnetovolume effect, ferroelectrorestriction and charge transfer) of thermal shrinkage and the development of NTE materials under each mechanism from both the theoretical and experimental aspects. Besides the low frequency optical phonons which are usually accepted as the origins of NTE in framework structures, NTE driven by acoustic phonons and the interplay between anisotropic elasticity and phonons are stressed. Based on the data documented, some problems affecting applications of NTE materials are discussed and strategies for discovering and design novel framework structured NET materials are also presented.
引用
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页数:37
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