Photochemical isomerization of 1,2,5-trisilabicyclo[3.2.0]hepta-3,6-diene to 1,4,7-trisilabicyclo[2.2.1]hepta-2,5-diene

被引：1

作者：

Matsuno, T ^{[1
]}

Ichinohe, M ^{[1
]}

Sekiguchi, A ^{[1
]}

机构：

[1] Univ Tsukuba, Dept Chem, Tsukuba, Ibaraki 3058571, Japan

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 10期

关键词：

D O I：

10.1039/b301536j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Upon irradiation of a benzene-d(6) solution of 1,2,2,5-tetrakis[ di-tert-butyl(methyl) silyl]-4,7-diaryl-1,2,5-trisilabicyclo[ 3.2.0] hepta-3,6-diene [1a: aryl = phenyl, b: aryl = 3,5-bis( trimethylsilyl) phenyl], 1,4,7,7-tetrakis[di-tert-butyl( methyl) silyl]-2,5-diaryl-1,4,7-trisilabicyclo[2.2.1] hepta-2,5- diene (2a, b) was formed via skeletal rearrangement.

引用

页码：1200 / 1201

页数：2

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