Copper-mediated aromatic amination reaction and its application to the total synthesis of natural products

被引：125
作者：
Okano, Kentaro [1 ]
Tokuyama, Hidetoshi [1 ]
Fukuyama, Tohru [2 ]
机构：
[1] Tohoku Univ, Grad Sch Pharmaceut Sci, Aoba Ku, Sendai, Miyagi 9808578, Japan
[2] Nagoya Univ, Grad Sch Pharmaceut Sci, Chikusa Ku, Nagoya, Aichi 4648601, Japan
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 89期
关键词：
C-H BONDS; PALLADIUM-CATALYZED AMINATION; CROSS-COUPLING REACTIONS; ARYL HALIDES; N-ARYLATION; INTRAMOLECULAR AMINATION; AMINO-ACIDS; AMIDATION; EFFICIENT; BROMIDES;
D O I：
10.1039/c4cc03895a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Herein, we review copper-mediated aromatic amination reactions including the classical Ullmann coupling and the recently developed mild aryl amination with an effective ligand as well as the C-H amination reaction. Several applications of intramolecular aryl amination to the syntheses of natural products demonstrate the general applicability of the reaction. © Partner Organisations 2014.
引用
收藏
页码：13650 / 13663
页数：14
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