Properties and characterization of novel cationic polyacrylate latex containing fluorine and silicon prepared with soap-free emulsion polymerization

被引：23

作者：

Li, Wen ^{[1
]}

Xu, Tingting ^{[1
]}

Zhang, Cuifeng ^{[1
]}

Bao, Zhongbin ^{[1
]}

Chen, Lijun ^{[1
]}

机构：

[1] Zhejiang Univ Technol, Sch Chem Engn, 18 Chaowang Rd, Hangzhou, Zhejiang, Peoples R China

来源：

JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY | 2016年 / 53卷 / 02期

关键词：

Acrylate; emulsion polymerization; fluorine; silicon; vinyltriethoxysilane;

D O I：

10.1080/10601325.2016.1121059

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The novel cationic polyacrylate latex containing fluorine silicon was successfully prepared via soap-free emulsion polymerization of butyl acrylate, methyl methacrylate, vinyltriethoxysilane and hexafluorobutylmethacrylate in water phase, which were initiated with water soluble azo initiator and emulsified with the mixed surfactants polymerizable emulsifier and OP-10. The films of the resultant latex were characterized by Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and contact angle (CA) determinator, respectively. In comparison with the conventional polyacrylate latex, the thermal stability and water resistance of novel latex film are improved. The conditions of preparing the novel cationic acrylate latexes were optimized. The optimum conditions of preparing the novel latex are as follows: the amount of emulsifiers and the initiator are 6.0% and0.3%, respectively; both the amount of VETS and amount of HFMA are 6.0%. In this case, the conversion is high and the polymerization stability is good.

引用

页码：104 / 110

页数：7

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