Reaction of tris(2-thienyl)phosphine with dirhodium(II) acetate.: Orthometalation of a heteroaromatic π-system and an unusual ring rearrangement

被引：16
作者：
Bieger, L
Estevan, F
Lahuerta, P
Lloret, J
Pérez-Prieto, J
Sanaú, M
Siguero, N
Stiriba, SE
机构：
[1] Univ Valencia, Fac Quim, Dept Quim Inorgan, E-46100 Valencia, Spain
[2] Univ Valencia, Fac Farm, Dept Quim Inorgan, Inst Ciencia Mol, E-46100 Valencia, Spain
来源：
ORGANOMETALLICS | 2003年 / 22卷 / 09期
关键词：
D O I：
10.1021/mo020976f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of tris (2-thienyl)phosphine (1) with dirhodium(II) acetate in a 9:1 refluxing toluene/ acetic acid mixture for 2 h leads to the formation of two metalated compounds. The structure of one of them contained two new orthometalated phosphines in a head-to-head arrangement, and, surprisingly, the metalated thiophene rings, but not the nonmetalated ones, were rearranged to a 3-thienyl structure. Both types of dirhodium compounds were assessed in a catalytic a-diazo ester transformation.
引用
收藏
页码：1799 / 1801
页数：3
相关论文
共 14 条
[1]   SYNTHESIS AND STRUCTURE OF THE ORTHO-METALATED DIRHODIUM(II) COMPOUND RH2(O2CCH3)3[(C6H4)P(C6H5)(C6F4BR)].P(C6H5)2(C6F4BR) [J].
BARCELO, F ;
COTTON, FA ;
LAHUERTA, P ;
LLUSAR, R ;
SANAU, M ;
SCHWOTZER, W ;
UBEDA, MA .
ORGANOMETALLICS, 1986, 5 (04) :808-811
[2]   STRUCTURAL AND ELECTROCHEMICAL CHARACTERIZATION OF THE NOVEL ORTHO-METALATED DIRHODIUM(II) COMPOUNDS RH2(O2CCH3)2[(C6H5)2P(C6H4)]2.2L [J].
CHAKRAVARTY, AR ;
COTTON, FA ;
TOCHER, DA ;
TOCHER, JH .
ORGANOMETALLICS, 1985, 4 (01) :8-13
[3]   Ligand effects on the chemoselectivity of ortho-metalated rhodium(II) catalyzed alpha-diazo ketone transformations [J].
Estevan, F ;
Lahuerta, P ;
PerezPrieto, J ;
Sanau, M ;
Stiriba, SE ;
Ubeda, MA .
ORGANOMETALLICS, 1997, 16 (05) :880-886
[4]   Reactivity and selectivity of ortho-metalated Rhodium(II) complexes in C-H insertion reactions of α-diazo compounds [J].
Estevan, F ;
Lahuerta, P ;
Perez-Prieto, J ;
Pereira, I ;
Stiriba, SE .
ORGANOMETALLICS, 1998, 17 (16) :3442-3447
[5]  
KELLOG RM, 1979, J ORG CHEM, V35, P2737
[6]   ORTHO-METALATION REACTIONS IN BINUCLEAR DIRHODIUM COMPOUNDS - MOLECULAR-STRUCTURE AND REACTIVITY OF A MONOMETALLATED COMPOUND WITH THE PHOSPHINE-P(ORTHO-CLC6H4)(C6H5)2 [J].
LAHUERTA, P ;
PAYA, J ;
SOLANS, X ;
UBEDA, MA .
INORGANIC CHEMISTRY, 1992, 31 (03) :385-391
[7]   REACTIONS OF RHODIUM TRIFLUOROACETATE WITH TRIPHENYLPHOSPHINE AND PYRIDINE - MOLECULAR-STRUCTURE OF RH2(O2CCF3)4(PY)4 [J].
LAHUERTA, P ;
UBEDA, MA ;
PAYA, J ;
GARCIAGRANDA, S ;
GOMEZBELTRAN, F ;
ANILLO, A .
INORGANICA CHIMICA ACTA, 1993, 205 (01) :91-97
[8]   ortho-metalated dirhodium(II)-catalyzed α-diazocarbonyl transformation.: Diastereoselective cyclopropanation of menthyl-α-diazo-β-keto ester and C-H insertion of α-diazo ester [J].
Lahuerta, P ;
Pereira, I ;
Pérez-Prieto, J ;
Sanaú, M ;
Stiriba, SE ;
Taber, DF .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 612 (1-2) :36-45
[9]  
LAHUERTA P, 1994, J CHEM SOC DA, P545
[10]   NEW ORTHO-METALLATED DIRHODIUM(II) COMPOUNDS [J].
MORRISON, EC ;
TOCHER, DA .
INORGANICA CHIMICA ACTA, 1989, 157 (02) :139-140
12