Second generation phenylene dendrimer, 1,3,5-tris[4-(3,5-diphenylphenyl)phenyl]benzene, as a precursor of a new carbon material

被引：3
|
作者：
Khotina, Irina A. [1 ]
Kushakova, Natalia S. [1 ]
Kharitonova, Victoria G. [1 ]
Kupriyanova, Daria V. [1 ]
Babich, Suria A. [1 ]
Kovalev, Alexey I. [1 ]
机构：
[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia
来源：
MENDELEEV COMMUNICATIONS | 2021年 / 31卷 / 03期
基金：
俄罗斯基础研究基金会;
关键词：
4-acetyl-3; 5; '-diphenyl(biphenyl); phenylene dendrimers; 1,3,5-tris[4-(3,5-diphenylphenyl)phenyl]benzene; thermal stability; INTRINSIC MICROPOROSITY; GAS-STORAGE; POLYMERS; POLYPHENYLENES; ADSORPTION; GENERATION; HYDROGEN; DIOXIDE; WATER;
D O I：
10.1016/j.mencom.2021.05.038
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A second generation phenylene dendrimer, viz. 1,3,5-tris[4-(3,5-diphenylphenyl)phenyl]benzene, was synthesized by cyclo-condensation of 4-acetyl-3',5'-diphenyl(biphenyl). This compound on heating to 600 degrees C is transformed into substance possessing extremely heat-stable secondary structure. It retains the aromatic structure at this temperature and when heated to 1000 degrees C is converted into material with graphite-like structure.
引用
收藏
页码：397 / 399
页数：3
相关论文
共 13 条
  • [1] SYNTHESIS AND CRYSTAL-STRUCTURE OF 1,3,5-TRIS[4 (PHENYLETHYNYL)PHENYL]BENZENE
    LINDEMAN, SV
    STRUCHKOV, YT
    KHOTINA, IA
    MIKHAILOV, VN
    RUSANOV, AL
    RUSSIAN CHEMICAL BULLETIN, 1994, 43 (11) : 1873 - 1879
  • [2] Synthesis and properties of hyperbranched polyamide-esters derived from 1,3,5-tris(4′-hydroxyphenylcarbamoyl)benzene
    Shabbir, Saima
    Zulfiqar, Sonia
    Ahmad, Zahoor
    Sarwar, Muhammad Ilyas
    TETRAHEDRON, 2010, 66 (06) : 1389 - 1398
  • [3] The Side Chain Makes the Difference: Investigation of the 2D Self-Assembly of 1,3,5-Tris[4-(4-pyridinyl)phenyl]benzene Derivatives by Scanning Tunneling Microscopy
    Trawny, Daniel
    Vandromme, Lucie
    Rabe, Juergen P.
    Reissig, Hans-Ulrich
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2014, 2014 (23) : 4985 - 4992
  • [4] Synthesis and characterization of hyperbranched aromatic polyester-imides with good thermal properties based on 1,3,5-tris(3′,4′-carboxyphenyl) benzene trianhydride
    Shabbir, Saima
    Zulfiqar, Sonia
    Ahmad, Zahoor
    Sarwar, Muhammad Ilyas
    POLYMER DEGRADATION AND STABILITY, 2010, 95 (07) : 1251 - 1259
  • [5] Experimental and theoretical investigations of 1,3,5-tris(4-aminophenoxy)benzene as an effective corrosion inhibitor for mild steel in 1 M HCl
    Zhou, Li
    Lv, Yan-Li
    Hu, Yong-Xu
    Zhao, Jin-Hui
    Xia, Xin
    Li, Xiao
    JOURNAL OF MOLECULAR LIQUIDS, 2018, 249 : 179 - 187
  • [6] Synthesis, structures and electrocatalytic properties of coordination polymers of 4,4′,4′′,4′′′-tetrakiscarboxyphenylsilane and 1,3,5-tris(2-methyl-1H-imidazol-1-yl)benzene
    Cao, Tingting
    Li, Yang
    Xie, Tinghui
    Wang, Xinfang
    Huang, Zuogang
    Yu, Huaguang
    CRYSTENGCOMM, 2024, 26 (07) : 985 - 994
  • [7] X3 synthon geometries in two-dimensional halogen-bonded 1,3,5-tris(3,5-dibromophenyl)-benzene self-assembled nanoarchitectures on Au(111)-(22 x √3)
    Peyrot, David
    Silly, Mathieu G.
    Silly, Fabien
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2018, 20 (06) : 3918 - 3924
  • [8] Hyperbranched cyclic and multicyclic poly(etherketone)s by polycondensation of isosorbide and isomannide with 2,6,4′-trifluorobenzophenone and 1,3,5-tris(4-fluorobenzoyl) benzene
    Bennour, Haythem
    Medimagh, Raouf
    Fildier, Aurelie
    Raffin, Guy
    Hangouet, Marie
    Chatti, Saber
    Zina, Mongia Said
    Kricheldorf, Hans R.
    HIGH PERFORMANCE POLYMERS, 2014, 26 (02) : 144 - 155
  • [9] Gas adsorption, magnetic, and fluorescent sensing properties of four coordination polymers based on 1,3,5-tris(4-carbonylphenyloxy)benzene and bis(imidazole) linkers
    Zhang, Jie
    Gao, Ling-Ling
    Zhai, Li-jun
    Wang, Xiao-Qing
    Fan, Li-Ming
    Hu, Tuo-Ping
    CRYSTENGCOMM, 2018, 20 (47): : 7666 - 7676
  • [10] From Au-Thiolate Chains to Thioether Sierpiriski Triangles: The Versatile Surface Chemistry of 1,3,5-Tris(4-mercaptophenyl)benzene on Au(111)
    Rastgoo-Lahrood, Atena
    Martsinovich, Natalia
    Lischka, Matthias
    Eichhorn, Johanna
    Szabelski, Pawel
    Nieckarz, Damian
    Strunskus, Thomas
    Das, Kalpataru
    Schmittel, Michael
    Heckl, Wolfgang M.
    Lackinger, Markus
    ACS NANO, 2016, 10 (12) : 10901 - 10911
12