Practical Use of Circular Dichroism and Vibrational Circular Dichroism for Structural Analysis

被引：5
作者：
Taniguchi, Tohru [1 ]
Monde, Kenji [1 ]
机构：
[1] Hokkaido Univ, Fac Adv Life Sci, Kita Ku, N21W11, Sapporo, Hokkaido 0010021, Japan
来源：
JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN | 2017年 / 75卷 / 05期
关键词：
circular dichroism; vibrational circular dichroism; configuration; conformation; DFT calculation; intramolecular interaction; intermolecular interaction; EXCITON CHIRALITY METHOD; DENSITY-FUNCTIONAL THEORY; ABSOLUTE-CONFIGURATION; VCD SPECTROSCOPY; OPTICAL-ACTIVITY; ASSIGNMENT; COMPLEXES; ACID;
D O I：
10.5059/yukigoseikyokaishi.75.522
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The use of theoretical calculations of circular dichroism (CD) and vibrational circular dichroism (VCD) spectroscopies for structural analysis has been becoming popular among organic chemists. In association with the conventional CD exciton chirality method and a recently-developed VCD exciton chirality method, proper use of CD and VCD spectroscopies should advance various studies related to chirality. This article briefly discusses the basics of structural analysis using theoretical calculations and the exciton chirality method of CD and VCD, with some tips and cautions for reliable spectral interpretation. The latter half of this article is dedicated to describing recent examples of the use of VCD for analyzing the configuration and conformation of small molecules, polymers, supramolecules, etc.
引用
收藏
页码：522 / 529
页数：8
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