A novel approach towards chemoselective reduction of nitro to amine

被引:13
作者
Dasgupta, Hridoydip Ranjan [1 ]
Mukherjee, Suvodip [1 ]
Ghosh, Pranab [1 ]
机构
[1] Univ North Bengal, Dept Chem, Siliguri, W Bengal, India
关键词
Chemo selective; Non-hazardous reducing agents; Aromatic nitro compound; Metal salt; GOLD NANOPARTICLES; CATALYZED REDUCTION; HYDROGEN DONOR; EFFICIENT; NITROARENES; OXIDE; NICKEL; NANOCOMPOSITE; MILD; ZINC;
D O I
10.1016/j.tetlet.2019.151028
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Chemo selective reduction of a wide range of aromatic nitro compound has been performed by using inexpensive Zn powder and CuSO4 system in water medium at room temperature. This system has high tolerance to other highly reducible groups present in nitro substance along with high conversation and selectivity. This chemo-selective reduction also provides a facile root for the synthesis of other industrially important fine chemicals or biologically important compounds where other highly reducible groups are present in close proximity to the targeted nitro groups. (C) 2019 Published by Elsevier Ltd.
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页数:5
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共 49 条
  • [11] Regio- and Chemoselective Reduction of Nitroarenes and Carbonyl Compounds over Recyclable Magnetic Ferrite-Nickel Nanoparticles (Fe3O4-Ni) by Using Glycerol as a Hydrogen Source
    Gawande, Manoj B.
    Rathi, Anuj K.
    Branco, Paula S.
    Nogueira, Isabel D.
    Velhinho, Alexandre
    Shrikhande, Janhavi J.
    Indulkar, Utkarsha U.
    Jayaram, Radha V.
    Ghumman, C. Amjad A.
    Bundaleski, Nenad
    Teodoro, Orlando M. N. D.
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (40) : 12628 - 12632
  • [12] Catalytic activation of hydrazine hydrate by gold nanoparticles: Chemoselective reduction of nitro compounds into amines
    Gkizis, Petros L.
    Stratakis, Manolis
    Lykakis, Ioannis N.
    [J]. CATALYSIS COMMUNICATIONS, 2013, 36 : 48 - 51
  • [13] Application of hydrazinium monoformate as new hydrogen donor with Raney nickel: a facile reduction of nitro and nitrile moieties
    Gowda, S
    Gowda, DC
    [J]. TETRAHEDRON, 2002, 58 (11) : 2211 - 2213
  • [14] Efficient and Selective Room-Temperature Gold-Catalyzed Reduction of Nitro Compounds with CO and H2O as the Hydrogen Source
    He, Lin
    Wang, Lu-Cun
    Sun, Hao
    Ni, Ji
    Cao, Yong
    He, He-Yong
    Ean, Kang-Nian
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (50) : 9538 - 9541
  • [15] Direct one-pot reductive imination of nitroarenes using aldehydes and carbon monoxide by titania supported gold nanoparticles at room temperature
    Huang, Jun
    Yu, Lei
    He, Lin
    Liu, Yong-Mei
    Cao, Yong
    Fan, Kang-Nian
    [J]. GREEN CHEMISTRY, 2011, 13 (10) : 2672 - 2677
  • [16] Nitrogen-Doped Graphene-Activated Iron-Oxide-Based Nanocatalysts for Selective Transfer Hydrogenation of Nitroarenes
    Jagadeesh, Rajenahally V.
    Natte, Kishore
    Junge, Henrik
    Beller, Matthias
    [J]. ACS CATALYSIS, 2015, 5 (03): : 1526 - 1529
  • [17] Efficient and highly selective iron-catalyzed reduction of nitroarenes
    Jagadeesh, Rajenahally V.
    Wienhoefer, Gerrit
    Westerhaus, Felix A.
    Surkus, Annette-Enrica
    Pohl, Marga-Martina
    Junge, Henrik
    Junge, Kathrin
    Beller, Matthias
    [J]. CHEMICAL COMMUNICATIONS, 2011, 47 (39) : 10972 - 10974
  • [18] Water as a direct hydrogen donor in supercritical carbon dioxide:: A novel and efficient Zn-H2O-CO2 system for chemoselective reduction of nitrobenzenes to anilines
    Jiang Huan-Feng
    Dong Yao-Sen
    [J]. CHINESE JOURNAL OF CHEMISTRY, 2008, 26 (08) : 1407 - 1410
  • [19] Copper(II) bromide as a procatalyst for in situ preparation of active Cu nanoparticles for reduction of nitroarenes
    Kadam, Hari K.
    Tilve, Santosh G.
    [J]. RSC ADVANCES, 2012, 2 (14): : 6057 - 6060
  • [20] Kock E., 1887, Chem. Ber, V20, P1567