Topological derivation from centrosymmetry to noncentrosymmetry in a three-dimensional polar framework material

被引：20

作者：

Wang, Fei ^{[1
]}

Zhang, Jian ^{[1
]}

Yu, Rongmin ^{[1
]}

Chen, Shu-Mei ^{[1
]}

Wu, Xiao-Yuan ^{[1
]}

Chen, Shan-Ci ^{[1
]}

Xie, Yi-Ming ^{[1
]}

Zhou, Wei-Wei ^{[1
]}

Lu, Can-Zhong ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 35002, Fujian, Peoples R China

来源：

CRYSTENGCOMM | 2010年 / 12卷 / 03期

关键词：

NONLINEAR-OPTICAL MATERIALS; METAL-ORGANIC FRAMEWORK; COORDINATION NETWORKS; POLYMERS; HYDROGEN; FILMS;

D O I：

10.1039/b915001c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Strong second harmonic generation (SHG) response was presented by a three-dimensional polar framework material [Cu-2(L)Br](n) (1; L = 5-(4-pyridyl)tetrazole), which was obtained by reacting CuBr with HL under solvothermal conditions and displayed an noncentrosymmetric (3,4)-connected topology derived from the centrosymmetric CdSO4 net.

引用

页码：671 / 673

页数：3

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