Preparation, characterization and anticorrosive properties of a novel polyaniline/clinoptilolite nanocomposite

被引：91

作者：

Olad, Ali ^{[1
]}

Naseri, Babak ^{[1
]}

机构：

[1] Univ Tabriz, Polymer Composite Res Lab, Dept Appl Chem, Fac Chem, Tabriz 5166614776, E Azarbayjan, Iran

来源：

PROGRESS IN ORGANIC COATINGS | 2010年 / 67卷 / 03期

关键词：

Polyaniline; Clinoptilolite; Zeolite; Nanocomposite; Corrosion; Conducting polymers; POLYANILINE; CHROMIUM(VI); REDUCTION; MMT;

D O I：

10.1016/j.porgcoat.2009.12.003

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Nanocomposite of polyaniline (PANI) with natural clinoptilolite (Clino) was prepared. Formation of nanocomposite and incorporation of polyaniline in the clinoptilolite channels was confirmed and characterized using FTIR spectroscopy studies. X-ray diffraction (XRD) pattern, scanning electron microscopy (SEM) and cyclic voltammetry techniques. The anticorrosive properties of a 20 mu m thickness coating of PANI/Clino nanocomposite with various weight ratios (1, 3 and 5%, w/w) of clinoptilolite content on iron Coupons was evaluated and compared with pure polyaniline coating. According to the results in acidic environments PANI/Clino nanocomposite has enhanced corrosion Protection effect in comparison to pure polyaniline coating. Comparative experiments revealed that PANI/Clino nanocomposite with 3% (w/w) clinoptilolite content has the best protective properties. Further experiments showed that the PANI/Clino nanocomposite has considerably different corrosion protection efficiencies in various corrosive environments. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：233 / 238

页数：6

共 20 条

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