High-entropy nanoparticles: Synthesis-structure-property relationships and data-driven discovery

被引：617

作者：

Yao, Yonggang ^{[1
]}

Dong, Qi ^{[1
]}

Brozena, Alexandra ^{[1
]}

Luo, Jian ^{[2
]}

Miao, Jianwei ^{[3
,4
]}

Chi, Miaofang ^{[5
]}

Wang, Chao ^{[6
]}

Kevrekidis, Ioannis G. ^{[6
]}

Ren, Zhiyong Jason ^{[7
,8
]}

Greeley, Jeffrey ^{[9
]}

Wang, Guofeng ^{[10
]}

Anapolsky, Abraham ^{[11
]}

Hu, Liangbing ^{[1
,12
]}

机构：

[1] Univ Maryland, Dept Mat Sci & Engn, College Pk, MD 20742 USA

[2] Univ Calif San Diego, Dept NanoEngn, Program Mat Sci & Engn, La Jolla, CA 92093 USA

[3] Univ Calif Los Angeles, Dept Phys & Astron, Los Angeles, CA 90095 USA

[4] Univ Calif Los Angeles, Calif NanoSyst Inst, Los Angeles, CA 90095 USA

[5] Oak Ridge Natl Lab, Ctr Nanophase Mat Sci, Oak Ridge, TN 37932 USA

[6] Johns Hopkins Univ, Dept Chem & Biomol Engn, Baltimore, MD 21218 USA

[7] Princeton Univ, Dept Civil & Environm Engn, Princeton, NJ 08544 USA

[8] Princeton Univ, Andlinger Ctr Energy & Environm, Princeton, NJ 08544 USA

[9] Purdue Univ, Sch Chem Engn, W Lafayette, IN 47907 USA

[10] Univ Pittsburgh, Dept Mech Engn & Mat Sci, Pittsburgh, PA 15261 USA

[11] Toyota Res Inst, Los Altos, CA 94022 USA

[12] Univ Maryland, Ctr Mat Innovat, College Pk, MD 20742 USA

来源：

SCIENCE | 2022年 / 376卷 / 6589期

基金：

美国国家科学基金会;

关键词：

SHOCK SYNTHESIS; CATALYSTS; PLATINUM; ALLOYS; ELECTROCATALYSTS; DESIGN; TRANSFORMATION; NUCLEATION; EVOLUTION; PARADIGM;

D O I：

10.1126/science.abn3103

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

High-entropy nanoparticles have become a rapidly growing area of research in recent years. Because of their multielemental compositions and unique high-entropy mixing states (i.e., solid-solution) that can lead to tunable activity and enhanced stability, these nanoparticles have received notable attention for catalyst design and exploration. However, this strong potential is also accompanied by grand challenges originating from their vast compositional space and complex atomic structure, which hinder comprehensive exploration and fundamental understanding. Through a multidisciplinary view of synthesis, characterization, catalytic applications, high-throughput screening, and data-driven materials discovery, this review is dedicated to discussing the important progress of high-entropy nanoparticles and unveiling the critical needs for their future development for catalysis, energy, and sustainability applications.

引用

页码：151 / +

页数：12

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