A Microporous Metal-Organic Framework Based on [2+2] Parallel and Inclined Interpenetrated 2D Sheets Interconnected by an Auxiliary Linker

被引：5
作者：
Song, Xiaokai [2 ]
Liu, Xinfang [2 ]
Oh, Minhak [1 ]
Lah, Myoung Soo [1 ]
机构：
[1] Ulsan Natl Inst Sci &Technol, Interdisciplinary Sch Green Energy, Ulsan 689805, South Korea
[2] Hanyang Univ, Dept Chem & Appl Chem, Ansan 426791, Kyunggi Do, South Korea
来源：
CRYSTAL GROWTH & DESIGN | 2010年 / 10卷 / 07期
基金：
新加坡国家研究基金会;
关键词：
SECONDARY BUILDING UNITS; HYDROGEN STORAGE; COORDINATION-POLYMER; NETWORK; POLYROTAXANE; SORPTION; NETS; ADSORPTION; CHANNELS; GUEST;
D O I：
10.1021/cg100357q
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A microporous metal organic framework (MOE), [Zn2L2(dabco)], was prepared using a long and rigid dicarboxylic acid, 1,4-bis(3-carboxylphenylethynyl)benzene (H2L), with some rotational flexibility, and an auxiliary bridging diamine linker, 1,4-diazabicyclo[2.2.2]octane (dabco). The MOE, based on a Zn paddle-wheel secondary building unit, has [2 + 2] parallel and inclined interpenetrating 2D sheets interconnected by dabco to form a 3D network with 1D helical channels.
引用
收藏
页码：3222 / 3227
页数：6
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