A Microporous Metal-Organic Framework Based on [2+2] Parallel and Inclined Interpenetrated 2D Sheets Interconnected by an Auxiliary Linker

被引：5
作者：
Song, Xiaokai [2 ]
Liu, Xinfang [2 ]
Oh, Minhak [1 ]
Lah, Myoung Soo [1 ]
机构：
[1] Ulsan Natl Inst Sci &Technol, Interdisciplinary Sch Green Energy, Ulsan 689805, South Korea
[2] Hanyang Univ, Dept Chem & Appl Chem, Ansan 426791, Kyunggi Do, South Korea
来源：
CRYSTAL GROWTH & DESIGN | 2010年 / 10卷 / 07期
基金：
新加坡国家研究基金会;
关键词：
SECONDARY BUILDING UNITS; HYDROGEN STORAGE; COORDINATION-POLYMER; NETWORK; POLYROTAXANE; SORPTION; NETS; ADSORPTION; CHANNELS; GUEST;
D O I：
10.1021/cg100357q
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A microporous metal organic framework (MOE), [Zn2L2(dabco)], was prepared using a long and rigid dicarboxylic acid, 1,4-bis(3-carboxylphenylethynyl)benzene (H2L), with some rotational flexibility, and an auxiliary bridging diamine linker, 1,4-diazabicyclo[2.2.2]octane (dabco). The MOE, based on a Zn paddle-wheel secondary building unit, has [2 + 2] parallel and inclined interpenetrating 2D sheets interconnected by dabco to form a 3D network with 1D helical channels.
引用
收藏
页码：3222 / 3227
页数：6
相关论文
共 55 条
[1]  
[Anonymous], 2008, MAT STUD PROGR VERS
[2]  
[Anonymous], 1997, SHELXTL PLUS CRYSTAL
[3]  
[Anonymous], 1997, SMART SAINT AR DET S
[4]   Poly(pseudo)rotaxane-like network mediated by hydrogen bonds in the solid-state structure of 1,7-phenanthroline [J].
Arora, KK ;
Pedireddi, VR .
CRYSTAL GROWTH & DESIGN, 2005, 5 (04) :1309-1312
[5]   Host-guest and network structures of some tetraphenylmethane derivatives [J].
Basavoju, S ;
Aitipamula, S ;
Desiraju, GR .
CRYSTENGCOMM, 2004, 6 :120-125
[6]  
Batten SR, 2000, CHEM-EUR J, V6, P156, DOI 10.1002/(SICI)1521-3765(20000103)6:1<156::AID-CHEM156>3.0.CO
[7]  
2-Y
[8]  
Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO
[9]  
2-Z
[10]   Topology of interpenetration [J].
Batten, SR .
CRYSTENGCOMM, 2001, (18)
123456