Crystal structure of the gold(I) complex [Au(tfp)Cl] with tfp =(C4H3O)3P

被引：4

作者：

Bachechi, F

Burini, A

Galassi, R

Pietroni, BR

机构：

[1] CNR, Ist Cristallog, Area Ric Roma, I-00016 Monterotondo, Roma, Italy

[2] Univ Camerino, Dipartimento Sci Chim, I-62032 Camerino, Italy

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2004年 / 34卷 / 11期

关键词：

gold complex; trifurylphosphine; X-Ray structure;

D O I：

10.1007/s10870-004-7649-9

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The Au(I) complex [Au(tfp)Cl] with tfp = (C4H3O)(3)P has been prepared and characterised. It crystallises in the monoclinic P2(1)/n space group with z = 4, a = 9.837(3), b = 12.684(4), c = 11. 103(5)Angstrom, beta = 91.58(2)degrees and V = 1384.8(2)Angstrom(3). The structure of the complex consists of molecules connected in head-to-tail dimers by a metal-halogen contact as generally found in analogus complexes of lighter coinage metals. The typical feature of halogen gold compounds, the Au-Au interaction, seems prevented by the bulk of the tfp ligand.

引用

页码：743 / 748

页数：6

共 18 条

[1] Comparative reactivity of palladium(0) complexes generated in situ in mixtures of triphenylphosphine or tri-2-furylphosphine and Pd(dba)2 [J].