Crystal structures of two furanosesquiterpenes from Commiphora sphaerocarpa

被引：37

作者：

Dekebo, A

Dagne, E

Hansen, LK

Gautun, OR

Aasen, AJ

机构：

[1] Univ Addis Ababa, Dept Chem, Addis Ababa, Ethiopia

[2] Univ Tromso, Dept Chem, N-9037 Tromso, Norway

[3] Univ Oslo, Sch Pharm, N-0316 Oslo, Norway

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 50期

关键词：

Commiphora sphaerocarpa; Burseraceae; C; myrrha; myrrh; furanosesquiterpenes; X-ray crystallography;

D O I：

10.1016/S0040-4039(00)01752-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The relative stereochemistry of a furanosesquiterpene, reported previously from myrrh, but isolated here from Commiphora sphaerocarpa is determined for the first time as (1(10)E,2R*,4R*)-2-methoxy-8,12-epoxygermacra-1(10),7,11-trien-6-one. Likewise the stereochemistry of furanodienone was established by NMR and X-ray crystallography as (1(10)E,4E)-8,12-epoxygermacra-1(10),4,7,11-tetrean-6-one. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：9875 / 9878

页数：4

共 11 条

[1] CONSTITUENTS OF THE ESSENTIAL OIL OF MYRRH .2. SESQUITERPENES AND FURANOSESQUITERPENES [J].