New tricks for an old dog:: The carbonate ion as a building block for networks including examples of composition [Cu6(CO3)12-{C(NH2)3}8]4- with the sodalite topology

被引：73

作者：

Abrahams, BF ^{[1
]}

Haywood, MG ^{[1
]}

Robson, R ^{[1
]}

Slizys, DA ^{[1
]}

机构：

[1] Univ Melbourne, Sch Chem, Parkville, Vic 3010, Australia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 10期

关键词：

cage compounds; carbonates; coordination polymers; guanidinium ion; sodalite;

D O I：

10.1002/anie.200390292

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cupric ions and carbonate ions, under the templating influence of pairs of hydrogen-bonding guanidinium ions, associate to form an infinite network with the topology of the 4264 sodalite net. This cage structure (see picture; for clarity, only copper centers and carbonate ions are shown) offers great scope for crystal engineering.

引用

页码：1112 / 1115

页数：4

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