New tricks for an old dog:: The carbonate ion as a building block for networks including examples of composition [Cu6(CO3)12-{C(NH2)3}8]4- with the sodalite topology

被引：73
作者：
Abrahams, BF [1 ]
Haywood, MG [1 ]
Robson, R [1 ]
Slizys, DA [1 ]
机构：
[1] Univ Melbourne, Sch Chem, Parkville, Vic 3010, Australia
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 10期
关键词：
cage compounds; carbonates; coordination polymers; guanidinium ion; sodalite;
D O I：
10.1002/anie.200390292
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Cupric ions and carbonate ions, under the templating influence of pairs of hydrogen-bonding guanidinium ions, associate to form an infinite network with the topology of the 4264 sodalite net. This cage structure (see picture; for clarity, only copper centers and carbonate ions are shown) offers great scope for crystal engineering.
引用
收藏
页码：1112 / 1115
页数：4
相关论文
共 14 条
  • [1] CRYSTAL-STRUCTURE OF COPPER(II) SODIUM CARBONATE TRIHYDRATE (CHALCONATRONITE)
    BROTHERT.PD
    WHITE, AH
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1973, (21): : 2338 - 2340
  • [2] Na2Zn3(CO3)(4)center dot 3H(2)O, a microporous sodium zincocarbonate with a diamond-type tetrahedral triangular topology
    Gier, TE
    Bu, XH
    Wang, SL
    Stucky, GD
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (12) : 3039 - 3040
  • [3] [CN3H6]2[ZN(CO3)2], the first organically templated open-framework carbonate
    Harrison, William T.A.
    Phillips, Mark L.F.
    Nenoff, Tina M.
    MacLean, Elizabeth J.
    Teat, Simon J.
    Maxwell, Robert S.
    [J]. 2001, Royal Society of Chemistry
  • [4] CRYSTAL-STRUCTURE AND PHYSICAL PROPERTIES OF ANHYDROUS SODIUM COPPER CARBONATE
    HEALY, PC
    WHITE, AH
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1972, (17): : 1913 - &
  • [5] MUELLER IM, 2000, ANGEW CHEM, V112, P4327
  • [6] Müller IM, 2000, ANGEW CHEM INT EDIT, V39, P4357, DOI 10.1002/1521-3773(20001201)39:23<4357::AID-ANIE4357>3.0.CO
  • [7] 2-0
  • [8] THE CHEMISTRY OF METAL CARBONATO AND CARBON-DIOXIDE COMPLEXES
    PALMER, DA
    VANELDIK, R
    [J]. CHEMICAL REVIEWS, 1983, 83 (06) : 651 - 731
  • [9] SYNTHESIS, STRUCTURE, AND PROPERTIES OF CUPRIC CARBONATE
    SEIDEL, H
    VISWANAT.K
    JOHANNES, W
    EHRHARDT, H
    [J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1974, 410 (02): : 138 - 148
  • [10] Sheldrick G. M., 1997, SHELX97: Program for Crystal Structure Refinement
12