Continuous Enantioselective Hydrogenation with a Molecular Catalyst in Supported Ionic Liquid Phase under Supercritical CO2 Flow

被引：79

作者：

Hintermair, Ulrich ^{[1
]}

Hoefener, Tobias ^{[1
]}

Pullmann, Thomas ^{[1
]}

Francio, Giancarlo ^{[1
]}

Leitner, Walter ^{[1
,2
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Tech & Makromol Chem, D-52074 Aachen, Germany

[2] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

来源：

CHEMCATCHEM | 2010年 / 2卷 / 02期

关键词：

catalyst immobilization; enantioselectivity; green chemistry; ionic liquids; supercritical fluids; ASYMMETRIC HYDROGENATION; SILP CATALYSIS; HOMOGENEOUS CATALYSIS; THIN-FILMS; HYDROFORMYLATION; COMPLEX; IMMOBILIZATION;

D O I：

10.1002/cctc.200900261

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

[No abstract available]

引用

页码：150 / 154

页数：5

共 39 条

[1] Recovery of organic products from ionic liquids using supercritical carbon dioxide [J].

Blanchard, LA ;

Brennecke, JF .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2001, 40 (01) :287-292

[2] Green processing using ionic liquids and CO2 [J].

Blanchard, LA ;

Hancu, D ;

Beckman, EJ ;

Brennecke, JF .

NATURE, 1999, 399 (6731) :28-29

[3]

Blaser H.U., 2004, ASYMMETRIC CATALYSIS

[4] Ruthenium-catalysed asymmetric hydrogenation of ketones using QUINAPHOS as the ligand [J].

Burk, S ;

Franciò, G ;

Leitner, W .

CHEMICAL COMMUNICATIONS, 2005, (27) :3460-3462

[5] Supported ionic-liquid films (SILF) as two-dimensional nanoreactors for enantioselective reactions:: Surface-mediated selectivity modulation (SMSM) [J].

Castillo, Maria R. ;

Fousse, Leslie ;

Fraile, Jose M. ;

Garcia, Jose I. ;

Mayoral, Jose A. .

CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (01) :287-291

[6]

Cole-Hamilton DJ, 2006, CATAL MET C, V30, P1, DOI 10.1007/1-4020-4087-3_1

[7]

Cornils B, 2005, MULTIPHASE HOMOGENEOUS CATALYSIS, VOLS 1 AND 2, P1, DOI 10.1002/9783527619597

[8] Heterogenisation of dimeric Cr(salen) with supported ionic liquids [J].

Dioos, Bart M. L. ;

Jacobs, Pierre A. .

JOURNAL OF CATALYSIS, 2006, 243 (01) :217-219

[9] Efficient heterogeneous asymmetric catalysis of the Mukaiyama aldol reaction by silica- and ionic liquid-supported Lewis acid copper(II) complexes of bis(oxazolines) [J].

Doherty, S. ;

Goodrich, P. ;

Hardacre, C. ;

Parvulescu, V. ;

Paun, C. .

ADVANCED SYNTHESIS & CATALYSIS, 2008, 350 (02) :295-302

[10] Enhanced enantioselectivity of chiral hydrogenation catalysts after immobilisation in thin films of ionic liquid [J].

Fow, Kam Loon ;

Jaenicke, Stephan ;

Mueller, Thomas E. ;

Sievers, Carsten .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2008, 279 (02) :239-247

← 1 2 3 4 →