Flame retardant and thermally insulating clay based aerogel facilitated by cellulose nanofibers

被引:56
作者
Gupta, Pragya [1 ]
Verma, Chhavi [1 ]
Maji, Pradip K. [1 ]
机构
[1] Indian Inst Technol Roorkee, Adv Mat Res Lab, Dept Polymer & Proc Engn, Saharanpur Campus, Saharanpur 247001, India
关键词
Sepiolite; Thermal conductivity; Flame retardant; Cellulose nanofibers; LOW-DENSITY; MECHANICAL-PROPERTIES; POLY(VINYL ALCOHOL); COMPOSITES; CONDUCTIVITY; FABRICATION;
D O I
10.1016/j.supflu.2019.05.005
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this paper, flame retardancy and thermal insulating properties of sepiolite clay and cellulose nanofibers based aerogel has been discussed. Due to the fragile characteristic of sepiolite based aerogel, cellulose nanofiber has been introduced into the clay to make it a composite aerogel. The prepared hybrid aerogel has been modified with a hydrophobic precursor i.e. Methyltrimethoxysilane (MTMS). Formation of aerogel has been confirmed by Field emission scanning electron microscope (FESEM) analysis and Brunauer-Emmett-Teller (BET) surface area measurement. The prepared specimens have shown the typical properties of aerogels like low density (11.5 kg/m(3) to 32.5 kg/m(3)), high porosity (99.2-98.3%) with good dimensional stability. Vertical burning test along with V-0 performance, horizontal burning test and flame penetration has confirmed its thermal shielding and flame retardancy. Thermal conductivity results also show good thermal insulation properties of prepared composite aerogel. (C) 2019 Elsevier B.V. All rights reserved.
引用
收藏
页数:12
相关论文
共 37 条
  • [1] Abramoff MD., 2004, BIOPHOTONICS INT, V11, P36, DOI DOI 10.1201/9781420005615.AX4
  • [2] Elastic, low density epoxy/clay aerogel composites
    Arndt, Eric M.
    Gawryla, Matthew D.
    Schiraldi, David A.
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (33) : 3525 - 3529
  • [3] Preparation and Flammability of Poly(vinyl alcohol) Composite Aerogels
    Chen, Hong-Bing
    Wang, Yu-Zhong
    Schiraldi, David A.
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (09) : 6790 - 6796
  • [4] Analysis of the hot-disk technique applied to low-density insulating materials
    Coquard, R.
    Coment, E.
    Flasquin, G.
    Baillis, D.
    [J]. INTERNATIONAL JOURNAL OF THERMAL SCIENCES, 2013, 65 : 242 - 253
  • [5] Toward aerogel based thermal superinsulation in buildings: A comprehensive review
    Cuce, Erdem
    Cuce, Pinar Mert
    Wood, Christopher J.
    Riffat, Saffa B.
    [J]. RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2014, 34 : 273 - 299
  • [6] Fabrication of Cellulose Nanofiber/AlOOH Aerogel for Flame Retardant and Thermal Insulation
    Fan, Bitao
    Chen, Shujun
    Yao, Qiufang
    Sun, Qingfeng
    Jin, Chunde
    [J]. MATERIALS, 2017, 10 (03):
  • [7] Eco-friendly Flame-Retardant Cellulose Nanofibril Aerogels by Incorporating Sodium Bicarbonate
    Farooq, Muhammad
    Sipponen, Mika H.
    Seppala, Ari
    Osterberg, Monika
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2018, 10 (32) : 27407 - 27415
  • [8] Advanced fabrication and oil absorption properties of super-hydrophobic recycled cellulose aerogels
    Feng, Jingduo
    Nguyen, Son T.
    Fan, Zeng
    Duong, Hai M.
    [J]. CHEMICAL ENGINEERING JOURNAL, 2015, 270 : 168 - 175
  • [9] pH Tailoring Electrical and Mechanical Behavior of Polymer-Clay-Nanotube Aerogels
    Gawryla, Matthew D.
    Liu, Lei
    Grunlan, Jaime C.
    Schiraldi, David A.
    [J]. MACROMOLECULAR RAPID COMMUNICATIONS, 2009, 30 (19) : 1669 - 1673
  • [10] All-natural and highly flame-resistant freeze-cast foams based on phosphorylated cellulose nanofibrils
    Ghanadpour, Maryam
    Wicklein, Bernd
    Carosio, Federico
    Wagberg, Lars
    [J]. NANOSCALE, 2018, 10 (08) : 4085 - 4095